Immobilization of selenate in cancrinite using a hydrothermal method

Niko Dian Pahlevi, Binglin Guo, Keiko Sasaki

研究成果: ジャーナルへの寄稿学術誌査読

12 被引用数 (Scopus)


Because of the Fukushima Daiichi Nuclear Power Plant (FDNPP) accident, radioactive species were leaked out, including selenium isotopes (79Se). Developing a stable matrix that is suitable for longterm storage is necessary for the decommissioning process of the FDNPP. In the present work, the co-precipitation of SeO42− in cancrinite/sodalite as a potential stable matrix was investigated at various reaction times using a hydrothermal method. Over time, the SeO42− contents in the solid products gradually increased. The XRD patterns revealed that the reaction produced multi-phased precipitates, which were zeolite Na (P), sodalite, and cancrinite. As the SeO42− amount increased, the solid products were transformed to cancrinite. The calculated lattice parameter of sodalite and cancrinite showed an increase in lattice parameter a for sodalite and cancrinite, suggesting SeO42− incorporated into the sodalite/cancrinite structure. XRD, SEM, FTIR, 27Al-NMR, and 29Si-NMR results revealed the phase transformation of the solid products over time. Four stages of the co-precipitation mechanism are proposed, including the formation of zeolite P (Na), hydroxylation of zeolite P (Na), the formation of sodalite, and cancrinite reprecipitation.

ジャーナルCeramics International
出版ステータス出版済み - 5月 2018

!!!All Science Journal Classification (ASJC) codes

  • 電子材料、光学材料、および磁性材料
  • セラミックおよび複合材料
  • プロセス化学およびプロセス工学
  • 表面、皮膜および薄膜
  • 材料化学


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