Improved Photocatalytic Hydrogen Evolution on Tantalate Perovskites CsTaO3 and LiTaO3 by Strain-Induced Vacancies

Kaveh Edalati, Keisuke Fujiwara, Shuhei Takechi, Qing Wang, Makoto Arita, Motonori Watanabe, Xavier Sauvage, Tatsumi Ishihara, Zenji Horita

    研究成果: Contribution to journalArticle査読

    16 被引用数 (Scopus)

    抄録

    Tantalate perovskites are potential candidates for photocatalytic hydrogen production without cocatalyst addition; however, these oxides have large bandgaps, which result in their low photocatalytic activity. In this study, to enhance the photocatalytic activity, CsTaO3 as a potential photocatalyst and LiTaO3 as a well-known photocatalyst are subjected to severe plastic strain using the high-pressure torsion (HPT) method. Both superstrained tantalates exhibit optical bandgap narrowing and ∼2.5 times enhancement of photocatalytic hydrogen production. Such bandgap narrowing is mainly due to the formation of oxygen vacancies, although nanocrystal formation and partial amorphization also occur by straining. These findings not only introduce CsTaO3 as a photocatalyst but also confirm the significance of strain-induced vacancies on the photocatalytic activity of perovskites.

    本文言語英語
    ページ(範囲)1710-1718
    ページ数9
    ジャーナルACS Applied Energy Materials
    3
    2
    DOI
    出版ステータス出版済み - 2 24 2020

    All Science Journal Classification (ASJC) codes

    • 化学工学(その他)
    • エネルギー工学および電力技術
    • 電気化学
    • 材料化学
    • 電子工学および電気工学

    フィンガープリント

    「Improved Photocatalytic Hydrogen Evolution on Tantalate Perovskites CsTaO<sub>3</sub> and LiTaO<sub>3</sub> by Strain-Induced Vacancies」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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