In situ powder neutron diffraction study of non-stoichiometric phase formation during the hydrogenation of Li3N

Daniel J. Bull, Natalie Sorbie, Gael Baldissin, David Moser, Mark T.F. Telling, Ronald I. Smith, Duncan H. Gregory, D. Keith Ross

研究成果: Contribution to journalArticle査読

6 被引用数 (Scopus)

抄録

The hydrogenation of Li3N at low chemical potential has been studied in situ by time-of-flight powder neutron diffraction and the formation of a non-stoichiometric Li4-2xNH phase and Li4NH observed. The results are interpreted in terms of a model for the reaction pathway involving the production of Li4NH and Li2NH, which subsequently react together to form Li4-2xNH. Possible mechanisms for the production of Li4NH from the hydrogenation of Li3N are discussed.

本文言語英語
ページ(範囲)263-270
ページ数8
ジャーナルFaraday Discussions
151
DOI
出版ステータス出版済み - 2011

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry

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