In situ powder neutron diffraction study of non-stoichiometric phase formation during the hydrogenation of Li3N

Daniel J. Bull; Natalie Sorbie; Gael Baldissin; David Moser; Mark T.F. Telling; Ronald I. Smith; Duncan H. Gregory; D. Keith Ross

doi:10.1039/c0fd00020e

In situ powder neutron diffraction study of non-stoichiometric phase formation during the hydrogenation of Li₃N

Daniel J. Bull, Natalie Sorbie, Gael Baldissin, David Moser, Mark T.F. Telling, Ronald I. Smith, Duncan H. Gregory, D. Keith Ross

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

11 被引用数 (Scopus)

抄録

The hydrogenation of Li₃N at low chemical potential has been studied in situ by time-of-flight powder neutron diffraction and the formation of a non-stoichiometric Li_4-2xNH phase and Li₄NH observed. The results are interpreted in terms of a model for the reaction pathway involving the production of Li₄NH and Li₂NH, which subsequently react together to form Li_4-2xNH. Possible mechanisms for the production of Li₄NH from the hydrogenation of Li₃N are discussed.

本文言語	英語
ページ（範囲）	263-270
ページ数	8
ジャーナル	Faraday Discussions
巻	151
DOI	https://doi.org/10.1039/c0fd00020e
出版ステータス	出版済み - 2011
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

医学（全般）

文献へのアクセス

10.1039/c0fd00020e

他のファイルとリンク

引用スタイル

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title = "In situ powder neutron diffraction study of non-stoichiometric phase formation during the hydrogenation of Li3N",

abstract = "The hydrogenation of Li3N at low chemical potential has been studied in situ by time-of-flight powder neutron diffraction and the formation of a non-stoichiometric Li4-2xNH phase and Li4NH observed. The results are interpreted in terms of a model for the reaction pathway involving the production of Li4NH and Li2NH, which subsequently react together to form Li4-2xNH. Possible mechanisms for the production of Li4NH from the hydrogenation of Li3N are discussed.",

author = "Bull, {Daniel J.} and Natalie Sorbie and Gael Baldissin and David Moser and Telling, {Mark T.F.} and Smith, {Ronald I.} and Gregory, {Duncan H.} and Ross, {D. Keith}",

year = "2011",

doi = "10.1039/c0fd00020e",

language = "English",

volume = "151",

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journal = "Faraday Discussions",

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publisher = "Royal Society of Chemistry",

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T1 - In situ powder neutron diffraction study of non-stoichiometric phase formation during the hydrogenation of Li3N

AU - Bull, Daniel J.

AU - Sorbie, Natalie

AU - Baldissin, Gael

AU - Moser, David

AU - Telling, Mark T.F.

AU - Smith, Ronald I.

AU - Gregory, Duncan H.

AU - Ross, D. Keith

PY - 2011

Y1 - 2011

N2 - The hydrogenation of Li3N at low chemical potential has been studied in situ by time-of-flight powder neutron diffraction and the formation of a non-stoichiometric Li4-2xNH phase and Li4NH observed. The results are interpreted in terms of a model for the reaction pathway involving the production of Li4NH and Li2NH, which subsequently react together to form Li4-2xNH. Possible mechanisms for the production of Li4NH from the hydrogenation of Li3N are discussed.

AB - The hydrogenation of Li3N at low chemical potential has been studied in situ by time-of-flight powder neutron diffraction and the formation of a non-stoichiometric Li4-2xNH phase and Li4NH observed. The results are interpreted in terms of a model for the reaction pathway involving the production of Li4NH and Li2NH, which subsequently react together to form Li4-2xNH. Possible mechanisms for the production of Li4NH from the hydrogenation of Li3N are discussed.

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JO - Faraday Discussions

JF - Faraday Discussions

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