TY - JOUR
T1 - Incorporation of a proton into La0.9Sr0.1(Yb 1 - XMx)O3 - δ (M = Y, In)
AU - Okuyama, Yuji
AU - Ikeda, Shohei
AU - Sakai, Takaaki
AU - Matsumoto, Hiroshige
N1 - Funding Information:
This study was supported by a Grant-in-Aid for Young Scientists (A) (No. 25709072 ) from Japan Society for the Promotion of Science and by the International Institute for Carbon Neutral Energy Research (WPI-I2CNER) , sponsored by the Japanese Ministry of Education, Culture, Sports, Science and Technology .
PY - 2014/9/1
Y1 - 2014/9/1
N2 - In order to clarify the mixing effect of cation on the electrical conductivity and the hydration, the electrical conductivity of La 0.9Sr0.1(Yb1 - xMx)O 3 - δ (M = In, Y) has been determined by the four-probe AC technique in the temperature range of 673-1173 K. The proton concentration was estimated from the change in weight due to hydration by a thermogravimetric analysis. The conductivity and proton concentration increased with the increase in the In3 + content on the Yb-site. On the other hand, the electrical conductivity and protonic concentration of La0.9Sr 0.1(Yb1 - xYx)O3 - δ showed minimum values at x = 0.5.
AB - In order to clarify the mixing effect of cation on the electrical conductivity and the hydration, the electrical conductivity of La 0.9Sr0.1(Yb1 - xMx)O 3 - δ (M = In, Y) has been determined by the four-probe AC technique in the temperature range of 673-1173 K. The proton concentration was estimated from the change in weight due to hydration by a thermogravimetric analysis. The conductivity and proton concentration increased with the increase in the In3 + content on the Yb-site. On the other hand, the electrical conductivity and protonic concentration of La0.9Sr 0.1(Yb1 - xYx)O3 - δ showed minimum values at x = 0.5.
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U2 - 10.1016/j.ssi.2013.11.044
DO - 10.1016/j.ssi.2013.11.044
M3 - Article
AN - SCOPUS:84903307121
VL - 262
SP - 865
EP - 869
JO - Solid State Ionics
JF - Solid State Ionics
SN - 0167-2738
ER -