抄録
(Chemical Equation Presented) Retro-aldol reaction: Indium-catalyzed reaction of a 1,3-diketone with an alcohol proceeds under solvent-free conditions by nucleophilic attack of the alcohol on a carbonyl group of the 1,3-diketone and carbon-carbon bond cleavage by a retro-Claisen condensation to give an ester in high yield (see scheme). Using water and an amine as nucleophiles instead of an alcohol gave the corresponding carboxylic acid and amide.
本文言語 | 英語 |
---|---|
ページ(範囲) | 7793-7795 |
ページ数 | 3 |
ジャーナル | Angewandte Chemie - International Edition |
巻 | 46 |
号 | 41 |
DOI | |
出版ステータス | 出版済み - 10 26 2007 |
外部発表 | はい |
All Science Journal Classification (ASJC) codes
- Chemistry(all)