抄録
(Chemical Equation Presented) Retro-aldol reaction: Indium-catalyzed reaction of a 1,3-diketone with an alcohol proceeds under solvent-free conditions by nucleophilic attack of the alcohol on a carbonyl group of the 1,3-diketone and carbon-carbon bond cleavage by a retro-Claisen condensation to give an ester in high yield (see scheme). Using water and an amine as nucleophiles instead of an alcohol gave the corresponding carboxylic acid and amide.
| 本文言語 | 英語 |
|---|---|
| ページ（範囲） | 7793-7795 |
| ページ数 | 3 |
| ジャーナル | Angewandte Chemie - International Edition |
| 巻 | 46 |
| 号 | 41 |
| DOI | |
| 出版ステータス | 出版済み - 10月 26 2007 |
| 外部発表 | はい |
!!!All Science Journal Classification (ASJC) codes
- 化学 (全般)