Indium-catalyzed retro-claisen condensation

Atsushi Kawata; Kazumi Takata; Yoichiro Kuninobu; Kazuhiko Takai

doi:10.1002/anie.200702798

Indium-catalyzed retro-claisen condensation

Atsushi Kawata, Kazumi Takata, Yoichiro Kuninobu, Kazuhiko Takai

研究成果: Contribution to journal › Article › 査読

93 被引用数 (Scopus)

抄録

(Chemical Equation Presented) Retro-aldol reaction: Indium-catalyzed reaction of a 1,3-diketone with an alcohol proceeds under solvent-free conditions by nucleophilic attack of the alcohol on a carbonyl group of the 1,3-diketone and carbon-carbon bond cleavage by a retro-Claisen condensation to give an ester in high yield (see scheme). Using water and an amine as nucleophiles instead of an alcohol gave the corresponding carboxylic acid and amide.

本文言語	英語
ページ（範囲）	7793-7795
ページ数	3
ジャーナル	Angewandte Chemie - International Edition
巻	46
号	41
DOI	https://doi.org/10.1002/anie.200702798
出版ステータス	出版済み - 10 26 2007
外部発表	はい

All Science Journal Classification (ASJC) codes

Chemistry(all)

文献へのアクセス

10.1002/anie.200702798

フィンガープリント「Indium-catalyzed retro-claisen condensation」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

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