Influences of water vapor on NASICON-based CO2 sensor operative at room temperature

Kenji Obata, Kengo Shimanoe, Norio Miura, Noboru Yamazoe

研究成果: ジャーナルへの寄稿Conference article

14 引用 (Scopus)

抄録

Electrochemical CO2 sensors were fabricated with NASICON (Na3Zr2Si2PO12) disks containing different levels of Na3PO4. The marked differences of the effect of aging in humid condition revealed that the auxiliary phase (NaHCO3 and/or Na2CO3) was formed spontaneously from the Na3PO4 impurity of NASICON in the presence of water vapor and CO2. Even when the auxiliary phase was formed or intentionally added, CO2 sensing properties were easily lost completely under exposure to dry atmosphere, indicating active involvement of water vapor in the CO2 sensing electrode reactions. EMF versus CO2 concentration correlations usually tended to shift up with increasing relative humidity. Remarkably, this shift was reduced effectively by introducing Li2CO3 as an auxiliary phase, suggesting that the shift originates from the instability of NaHCO3 and/or Na2CO3 in humid atmosphere.

元の言語英語
ページ(範囲)243-249
ページ数7
ジャーナルSensors and Actuators, B: Chemical
93
発行部数1-3
DOI
出版物ステータス出版済み - 8 1 2003
イベントProceedings of the Ninth International Meeting on Chemical Engineering - Boston, MA, 米国
継続期間: 7 7 20037 10 2003

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Steam
Water vapor
water vapor
Electrochemical sensors
shift
sensors
Sensors
room temperature
atmospheres
Atmospheric humidity
Aging of materials
Impurities
Temperature
Electrodes
humidity
Electric potential
impurities
electrodes

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Instrumentation
  • Condensed Matter Physics
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Electrical and Electronic Engineering
  • Materials Chemistry

これを引用

Influences of water vapor on NASICON-based CO2 sensor operative at room temperature. / Obata, Kenji; Shimanoe, Kengo; Miura, Norio; Yamazoe, Noboru.

:: Sensors and Actuators, B: Chemical, 巻 93, 番号 1-3, 01.08.2003, p. 243-249.

研究成果: ジャーナルへの寄稿Conference article

Obata, Kenji ; Shimanoe, Kengo ; Miura, Norio ; Yamazoe, Noboru. / Influences of water vapor on NASICON-based CO2 sensor operative at room temperature. :: Sensors and Actuators, B: Chemical. 2003 ; 巻 93, 番号 1-3. pp. 243-249.
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AB - Electrochemical CO2 sensors were fabricated with NASICON (Na3Zr2Si2PO12) disks containing different levels of Na3PO4. The marked differences of the effect of aging in humid condition revealed that the auxiliary phase (NaHCO3 and/or Na2CO3) was formed spontaneously from the Na3PO4 impurity of NASICON in the presence of water vapor and CO2. Even when the auxiliary phase was formed or intentionally added, CO2 sensing properties were easily lost completely under exposure to dry atmosphere, indicating active involvement of water vapor in the CO2 sensing electrode reactions. EMF versus CO2 concentration correlations usually tended to shift up with increasing relative humidity. Remarkably, this shift was reduced effectively by introducing Li2CO3 as an auxiliary phase, suggesting that the shift originates from the instability of NaHCO3 and/or Na2CO3 in humid atmosphere.

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