抄録
We report the first example of a wholly inorganic mimic of a part of the FeMoco active centre of nitrogenases. We detail the synthesis, characterisation and reactivity of two related, transient hydride-containing inorganic clusters, a dihydride complex and a vinyl monohydride complex, which bear the [Fe2MoOS3] portion of FeMoco. The dihydride complex is capable of reducing acetylene to ethylene via the vinyl monohydride complex. In the reaction cycle, a transient low-valent complex was generated by the reductive elimination of H2 or ethylene from dihydride or vinyl monohydride complexes, respectively.
本文言語 | 英語 |
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ページ(範囲) | 14620-14627 |
ページ数 | 8 |
ジャーナル | Dalton Transactions |
巻 | 45 |
号 | 37 |
DOI | |
出版ステータス | 出版済み - 2016 |
!!!All Science Journal Classification (ASJC) codes
- 無機化学