Insertion of a strongly π-π stacked chloranilate pair into an M4 arrangement preorganized within a large macrocyclic ligand (M = Zn2+ and Cu2+)

Atsushi Yoshino; Hideo Matsudaira; Eiji Asato; Masayuki Koikawa; Takuya Shiga; Masaaki Ohba; Hisashi Okawa

doi:10.1039/b202529a

Insertion of a strongly π-π stacked chloranilate pair into an M₄ arrangement preorganized within a large macrocyclic ligand (M = Zn²⁺ and Cu²⁺)

Atsushi Yoshino, Hideo Matsudaira, Eiji Asato, Masayuki Koikawa, Takuya Shiga, Masaaki Ohba, Hisashi Okawa

無機・分析化学

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

9 被引用数 (Scopus)

抄録

Four Zn(ii) ions arranged within a pyridine-modified large phenolate-containing macrocycle L_py²⁻ encapsulate two chloranilate ions in a double bis-didentate bridging fashion; the ligands are strongly π-π stacked with each other with a short distance of 3.27 A and are electrochemically reduced at the same potential of - 1.00 V to produce a reasonably stable biradical species with T _1/2 = 60 min at 25 °C.

本文言語	英語
ページ（範囲）	1258-1259
ページ数	2
ジャーナル	Chemical Communications
巻	2
号	12
DOI	https://doi.org/10.1039/b202529a
出版ステータス	出版済み - 1月 1 2002

!!!All Science Journal Classification (ASJC) codes

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

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10.1039/b202529a

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引用スタイル

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abstract = "Four Zn(ii) ions arranged within a pyridine-modified large phenolate-containing macrocycle Lpy2− encapsulate two chloranilate ions in a double bis-didentate bridging fashion; the ligands are strongly π-π stacked with each other with a short distance of 3.27 A and are electrochemically reduced at the same potential of - 1.00 V to produce a reasonably stable biradical species with T 1/2 = 60 min at 25 °C.",

author = "Atsushi Yoshino and Hideo Matsudaira and Eiji Asato and Masayuki Koikawa and Takuya Shiga and Masaaki Ohba and Hisashi Okawa",

year = "2002",

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T1 - Insertion of a strongly π-π stacked chloranilate pair into an M4 arrangement preorganized within a large macrocyclic ligand (M = Zn2+ and Cu2+)

AU - Yoshino, Atsushi

AU - Matsudaira, Hideo

AU - Asato, Eiji

AU - Koikawa, Masayuki

AU - Shiga, Takuya

AU - Ohba, Masaaki

AU - Okawa, Hisashi

PY - 2002/1/1

Y1 - 2002/1/1

N2 - Four Zn(ii) ions arranged within a pyridine-modified large phenolate-containing macrocycle Lpy2− encapsulate two chloranilate ions in a double bis-didentate bridging fashion; the ligands are strongly π-π stacked with each other with a short distance of 3.27 A and are electrochemically reduced at the same potential of - 1.00 V to produce a reasonably stable biradical species with T 1/2 = 60 min at 25 °C.

AB - Four Zn(ii) ions arranged within a pyridine-modified large phenolate-containing macrocycle Lpy2− encapsulate two chloranilate ions in a double bis-didentate bridging fashion; the ligands are strongly π-π stacked with each other with a short distance of 3.27 A and are electrochemically reduced at the same potential of - 1.00 V to produce a reasonably stable biradical species with T 1/2 = 60 min at 25 °C.

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