Insight into lithium transport in lithium nitridometallate battery materials from muon spin relaxation

Andrew S. Powell, Zlatka Stoeva, James S. Lord, Ronald I. Smith, Duncan H. Gregory, Jeremy J. Titman

研究成果: ジャーナルへの寄稿学術誌査読

14 被引用数 (Scopus)

抄録

Muon spin relaxation and powder neutron diffraction have been combined to study three lithium cobalt nitride battery materials. Neutron diffraction shows that these retain the P6/mmm space group of Li3N with Co located only on Li(1) sites. The lattice parameters vary smoothly with the degree of metal substitution, such that the [Li2N] layers expand while the layer separation contracts, as observed previously for similar series of Cu- and Ni-substituted materials. However, in contrast to the latter, the Li 3-x-yCoxN phases exhibit Curie-Weiss paramagnetism and this prevents the use of nuclear magnetic resonance to measure Li+ transport parameters. Therefore, muon spin relaxation has been employed here as an alternative technique to obtain quantitative information about Li+ diffusion. Muon spin relaxation shows that Li+ diffusion in Li 3-x-yCoxN is anisotropic with transport confined to the [Li2N] plane at low temperature and exchange between Li(1) and Li(2) sites dominant at high temperature. By a comparison with previous studies some general trends have been established across a range of Cu-, Ni- and Co-substituted materials. For intra-layer diffusion Ea decreases as metal substitution increases and the corresponding expansion of the layers results in a more open pathway for Li+ diffusion. However, an optimal value of x is found with a ≈ 3.69 Å after which the concomitant contraction in layer spacing reduces the polarizability of the lattice framework.

本文言語英語
ページ(範囲)816-823
ページ数8
ジャーナルPhysical Chemistry Chemical Physics
15
3
DOI
出版ステータス出版済み - 1月 21 2013
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 物理学および天文学(全般)
  • 物理化学および理論化学

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