Interaction of linear metal triazole complexes with liquid crystals and their gel formations

研究成果: 会議への寄与タイプ論文

抜粋

Transition metal complexes of aliphatic triazole M(1)3Cl 2 (M: Fe, Co) (1: C12OC3Trz, M = Co(II), Fe(II)) gives heat-set gel-like networks in organic media. In this study, we investigated their interaction with liquid crystal molecules. When liquid crystal (JC-1041XX) was added to M(1)3Cl2 (M: Fe, Co) in CHCl3at a weight ratio of 9:1, stable organogels were obtained. They show reversible spin transition (FeII) and coordination changes (CoII), without dissolution of the gels. Apparently, nanofibrous assemblies of M(1)3Cl2 were stabilized by the interaction with liquid crystal molecules. Freeze-dried chloroform gels showed nematic liquid crystals as observed by polarized optical microscopy. The metal complexes in liquid crystals would provide a new research area in materials chemistry.

元の言語英語
ページ数1
出版物ステータス出版済み - 12 1 2005
イベント54th SPSJ Annual Meeting 2005 - Yokohama, 日本
継続期間: 5 25 20055 27 2005

その他

その他54th SPSJ Annual Meeting 2005
日本
Yokohama
期間5/25/055/27/05

    フィンガープリント

All Science Journal Classification (ASJC) codes

  • Engineering(all)

これを引用

Kuroiwa, K., Kimizuka, N., & Kikuchi, H. (2005). Interaction of linear metal triazole complexes with liquid crystals and their gel formations. 論文発表場所 54th SPSJ Annual Meeting 2005, Yokohama, 日本.