Interaction of linear metal triazole complexes with liquid crystals and their gel formations

研究成果: 会議への寄与タイプ学会誌査読

抄録

Transition metal complexes of aliphatic triazole M(1)3Cl 2 (M: Fe, Co) (1: C12OC3Trz, M = Co(II), Fe(II)) gives heat-set gel-like networks in organic media. In this study, we investigated their interaction with liquid crystal molecules. When liquid crystal (JC-1041XX) was added to M(1)3Cl2 (M: Fe, Co) in CHCl3at a weight ratio of 9:1, stable organogels were obtained. They show reversible spin transition (FeII) and coordination changes (CoII), without dissolution of the gels. Apparently, nanofibrous assemblies of M(1)3Cl2 were stabilized by the interaction with liquid crystal molecules. Freeze-dried chloroform gels showed nematic liquid crystals as observed by polarized optical microscopy. The metal complexes in liquid crystals would provide a new research area in materials chemistry.

本文言語英語
ページ数1
出版ステータス出版済み - 12月 1 2005
イベント54th SPSJ Annual Meeting 2005 - Yokohama, 日本
継続期間: 5月 25 20055月 27 2005

その他

その他54th SPSJ Annual Meeting 2005
国/地域日本
CityYokohama
Period5/25/055/27/05

!!!All Science Journal Classification (ASJC) codes

  • 工学(全般)

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