Interatomic distances in layered silicates and their intercalation compounds as studied by cross polarization NMR

Shigenobu Hayashi, Etsuo Akiba

研究成果: ジャーナルへの寄稿学術誌査読

18 被引用数 (Scopus)

抄録

Contact time dependences of signal intensities in 29Si and 13C CP/MAS NMR have been measured for kaolinite and kaolinite-dimethylsulphoxide (DMSO) and kaolinite-DMSO-d6 intercalation compounds. Cross relaxation times between 1H and 29Si and between 1H and 13C have been estimated experimentally, which reflect the internuclear distances. Relaxation times have been calculated theoretically using reported crystal structure models, and we have discussed the validity of those models.

本文言語英語
ページ(範囲)495-500
ページ数6
ジャーナルChemical Physics Letters
226
5-6
DOI
出版ステータス出版済み - 8月 26 1994
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 物理学および天文学(全般)
  • 物理化学および理論化学

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