Intercalation-induced esterification over a layered transition metal oxide

Atsushi Takagaki, Ryo Sasaki, Caio Tagusagawa, Kazunari Domen

研究成果: Contribution to journalArticle査読

24 被引用数 (Scopus)

抄録

The layered transition metal oxide HNbMoO6 is demonstrated to catalyze the esterification of lactic acid (a hydroxycarboxylic acid) with activity superior or comparable to conventional ion-exchange resins. Layered HNbMoO6 also catalyzes the esterification of propionic acid (a carboxylic acid) in the presence of lactic acid, despite exhibiting negligible activity for any carboxylic acid as the sole reactant. X-ray diffraction (XRD) measurements indicate that lactic acid is intercalated into the interlayer structure of the oxide whereas carboxylic acid is not. The intercalation mechanism thus greatly affects the catalytic activity of this layered catalyst.

本文言語英語
ページ(範囲)592-596
ページ数5
ジャーナルTopics in Catalysis
52
6-7
DOI
出版ステータス出版済み - 6 2009
外部発表はい

All Science Journal Classification (ASJC) codes

  • 触媒
  • 化学 (全般)

フィンガープリント

「Intercalation-induced esterification over a layered transition metal oxide」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル