Interfacial profiles of miscible poly(4-trimethylsilylstyrene)/ polyisoprene bilayer films

Masashi Harada, Takahisa Suzuki, Masayuki Ohya, Daisuke Kawaguchi, Atsushi Takano, Yushu Matsushita, Naoya Torikai

研究成果: Contribution to journalArticle査読

16 被引用数 (Scopus)


Compositional profiles of bilayer films in the direction normal to the interfaces have been investigated by neutron reflectivity measurements and analyzed with mean field theory. The bilayer films were prepared with poly(4-trimethylsilylstyrene) (PTMSS) and polyisoprene (PI), which constitute a miscible polymer pair and whose blends show phase separation at the lower critical solution temperature (LCST) by heating. Because we can accurately control the degree of polymerization of component polymers and can adjust the Flory-Huggins interaction parameter, χ, with the temperature, T, according to the relationship χ = 0.027-9.5/T, the phase behavior and the interfacial structure of PTMSS and PI are predictable by mean field theory. When the bilayer films of PTMSS and PI were set at 90 °C, which is a temperature below the LCST, diffusion at the interface was observed, and the original interface disappeared in several hours; this supports the idea that the polymer pair is miscible. No clear interfaces were identified below the LCST, whereas broad interfaces, compared with that of the strong segregation pairs, were observed above the LCST. The compositions of each layer are consistent with that of the coexisting phase in the polymer blends, and the interfacial widths agree well with the theoretical prediction considering the effect of capillary waves. In addition, all annealed films have a thin surface layer of PTMSS corresponding to surface segregation induced by the lower surface energy of PTMSS (with respect to that of PI). Thus, the interfacial profiles of PTMSS/PI bilayer films have been totally prospected in the framework of mean field theory. (c)

ジャーナルJournal of Polymer Science, Part B: Polymer Physics
出版ステータス出版済み - 6 15 2005

All Science Journal Classification (ASJC) codes

  • 凝縮系物理学
  • 物理化学および理論化学
  • ポリマーおよびプラスチック
  • 材料化学


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