Iron-catalysed cross-coupling of halohydrins with aryl aluminium reagents: A protecting-group-free strategy attaining remarkable rate enhancement and diastereoinduction

Shintaro Kawamura, Tatsuya Kawabata, Kentaro Ishizuka, Masaharu Nakamura

    研究成果: Contribution to journalArticle査読

    38 被引用数 (Scopus)

    抄録

    Non-protected halohydrins are cross-coupled with aryl aluminium reagents to produce aryl alkanols in the presence of the iron–bisphosphine catalysts. Remarkable reaction rate enhancement and diastereoinduction are realized by the in situ generated aluminium alkoxides, offering a new method for the reactivity and selectivity control of the iron-catalysed cross-coupling reaction. 2012

    本文言語英語
    ページ(範囲)9376-9378
    ページ数3
    ジャーナルChemical Communications
    48
    75
    DOI
    出版ステータス出版済み - 8 22 2012

    All Science Journal Classification (ASJC) codes

    • Catalysis
    • Electronic, Optical and Magnetic Materials
    • Ceramics and Composites
    • Chemistry(all)
    • Surfaces, Coatings and Films
    • Metals and Alloys
    • Materials Chemistry

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