Isotopic effect of proton conductivity in gadolinium sesquioxide

M. Khalid Hossain, K. Kawaguchi, K. Hashizume

研究成果: Contribution to journalArticle査読

7 被引用数 (Scopus)

抄録

Due to the higher hydrogen solubility and diffusivity, gadolinium sesquioxide (Gd2O3) could be expected as a proton conductive material. In this study, monoclinic Gd2O3 was used to evaluate the possible proton conductivity in Ar (σAr), Ar+4% H2H2), Ar+4% D2D2), Ar+H2O (σH2O), Ar+D2O (σD2O), and O2O2) atmospheres in the temperature range from 500°C to 1000°C, to understand its possible application in the DT fuel system of a nuclear fusion reactor. At all temperatures, the conductivity σD2 was lower than that of the σH2. Similarly, the σD2O was always lower than that of the σH2O. The isotope dependence was appreciable at higher temperatures, indicating that Gd2O3 is a proton-conductive oxide at elevated temperatures. However, much improvement is required for the use of Gd2O3 in the DT fuel recovery, analysis, and purification system of fusion reactors.

本文言語英語
論文番号112555
ジャーナルFusion Engineering and Design
171
DOI
出版ステータス出版済み - 10 2021

All Science Journal Classification (ASJC) codes

  • 土木構造工学
  • 原子力エネルギーおよび原子力工学
  • 材料科学(全般)
  • 機械工学

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