Jiangrine-like scaffolds from biorenewable platforms

Rory Devlin, Shinji Kudo, Jonathan Sperry

研究成果: Contribution to journalArticle査読

1 被引用数 (Scopus)

抄録

Dihydrolevoglucosenone (DLGO) and amino aldehydes undergo an aldol reaction mediated by the heterogenous base KF-alumina; exposure of the aldol adducts to hydrogenation followed by silica gel results in the formation of pyrrole-2-carbaldehydes bearing the jiangrine alkaloid scaffold. KF-alumina is also an effective base in the aldol condensation between DLGO and aliphatic/aromatic aldehydes, with no self-aldol reaction apparent.

本文言語英語
論文番号152538
ジャーナルTetrahedron Letters
61
47
DOI
出版ステータス出版済み - 11 19 2020

All Science Journal Classification (ASJC) codes

  • 生化学
  • 創薬
  • 有機化学

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