Kinetics of the reaction between Mg2Ni and hydrogen

K. Nomura, E. Akiba, S. Ono

研究成果: ジャーナルへの寄稿学術誌査読

69 被引用数 (Scopus)

抄録

The reaction between Mg2Ni and hydrogen was investigated by volumetric method. The reaction was divided into two stages; the initial stage was a very rapid reaction whose rate could not be measured, the later stage was the slower step whose rate was expressed by the equation dn/DT=K′(P-Peq/t where k′ is the constant, Peq and P are hydrogen pressures at equilibrium and at time t. The reaction rate of the later stage did not depend upon temperature, content of hydrogen in the alloy, and directions of the reaction, desorption and absorption. The amount of reacted hydrogen, Δn, in the initial stage was expressed by Δn=k(Po-Peq)(ns-no where P0 is the initial hydrogen pressure, ns is a constant around 4, n0 is a ratio of H to Mg2Ni at the initiation of the run, and k is a constant. The apparent activation energy of the reaction was nearly zero. It is considered that the reaction between the alloy and gaseous hydrogen takes place on metallic Mg2Ni in the initial stage and in the later stage reaction proceeds on the deactivated site.

本文言語英語
ページ(範囲)295-303
ページ数9
ジャーナルInternational Journal of Hydrogen Energy
6
3
DOI
出版ステータス出版済み - 1月 1 1981
外部発表はい

All Science Journal Classification (ASJC) codes

  • 再生可能エネルギー、持続可能性、環境
  • 燃料技術
  • 凝縮系物理学
  • エネルギー工学および電力技術

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