Lewis acid-specific polymerization behaviors in living cationic polymerization of vinyl ether with a malonate group

Yukari Oda; Tomohiro Tsujino; Shokyoku Kanaoka; Sadahito Aoshima

doi:10.1002/pola.26088

Lewis acid-specific polymerization behaviors in living cationic polymerization of vinyl ether with a malonate group

Yukari Oda, Tomohiro Tsujino, Shokyoku Kanaoka, Sadahito Aoshima

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

8 被引用数 (Scopus)

抄録

For the precision synthesis of carboxy-functional polymers, the cationic polymerization of a malonic ester-containing vinyl ether (VOEM) was examined with various Lewis acids in the presence of an added base. Living cationic polymerization was achieved using ZnCl ₂, FeCl ₃, and SnCl ₄ in conjunction with a suitable added base, whereas TiCl ₄ and Et _1.5AlCl _1.5 only led to oligomerization. Such significant differences in polymerization behavior resulted from the interactions of the diester groups with a particular Lewis acid.

本文言語	英語
ページ（範囲）	2993-2998
ページ数	6
ジャーナル	Journal of Polymer Science, Part A: Polymer Chemistry
巻	50
号	15
DOI	https://doi.org/10.1002/pola.26088
出版ステータス	出版済み - 8月 1 2012
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

ポリマーおよびプラスチック
有機化学
材料化学

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title = "Lewis acid-specific polymerization behaviors in living cationic polymerization of vinyl ether with a malonate group",

abstract = "For the precision synthesis of carboxy-functional polymers, the cationic polymerization of a malonic ester-containing vinyl ether (VOEM) was examined with various Lewis acids in the presence of an added base. Living cationic polymerization was achieved using ZnCl 2, FeCl 3, and SnCl 4 in conjunction with a suitable added base, whereas TiCl 4 and Et 1.5AlCl 1.5 only led to oligomerization. Such significant differences in polymerization behavior resulted from the interactions of the diester groups with a particular Lewis acid.",

author = "Yukari Oda and Tomohiro Tsujino and Shokyoku Kanaoka and Sadahito Aoshima",

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T1 - Lewis acid-specific polymerization behaviors in living cationic polymerization of vinyl ether with a malonate group

AU - Oda, Yukari

AU - Tsujino, Tomohiro

AU - Kanaoka, Shokyoku

AU - Aoshima, Sadahito

PY - 2012/8/1

Y1 - 2012/8/1

N2 - For the precision synthesis of carboxy-functional polymers, the cationic polymerization of a malonic ester-containing vinyl ether (VOEM) was examined with various Lewis acids in the presence of an added base. Living cationic polymerization was achieved using ZnCl 2, FeCl 3, and SnCl 4 in conjunction with a suitable added base, whereas TiCl 4 and Et 1.5AlCl 1.5 only led to oligomerization. Such significant differences in polymerization behavior resulted from the interactions of the diester groups with a particular Lewis acid.

AB - For the precision synthesis of carboxy-functional polymers, the cationic polymerization of a malonic ester-containing vinyl ether (VOEM) was examined with various Lewis acids in the presence of an added base. Living cationic polymerization was achieved using ZnCl 2, FeCl 3, and SnCl 4 in conjunction with a suitable added base, whereas TiCl 4 and Et 1.5AlCl 1.5 only led to oligomerization. Such significant differences in polymerization behavior resulted from the interactions of the diester groups with a particular Lewis acid.

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DO - 10.1002/pola.26088

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JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 15

ER -

Lewis acid-specific polymerization behaviors in living cationic polymerization of vinyl ether with a malonate group

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!!!All Science Journal Classification (ASJC) codes

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