Lewis base assisted Brønsted base catalysis: Bidentate phosphine oxides as activators and modulators of brønsted basic lanthanum-aryloxides

Hiroyuki Morimoto, Tatsuhiko Yoshino, Takafumi Yukawa, Gang Lu, Shigeki Matsunaga, Masakatsu Shibasaki

研究成果: ジャーナルへの寄稿記事

42 引用 (Scopus)

抜粋

(Chemical Equation Presented) Dynamic Duo: A Lewis basic bidentate phosphine oxide was effective for activating and modulating the properties of Brønsted basic lanthanum aryl oxides. The Lewis base 1/lanthanum aryl oxide system was suitable for anti-selective Mannich-type reactions of trichloromethyl ketones (see scheme), affording unique building blocks for azetidine-2-carboxylic acids as well as β-amino acids.

元の言語英語
ページ(範囲)9125-9129
ページ数5
ジャーナルAngewandte Chemie - International Edition
47
発行部数47
DOI
出版物ステータス出版済み - 11 10 2008
外部発表Yes

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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