Light-mediated oxidation of alcohols and mandelate by flavin-metal complexes

Seiji Shinkai, Hideki Nakao, Kaori Ueda, Osamu Manabe

研究成果: Contribution to journalArticle査読

15 被引用数 (Scopus)

抄録

New flavins with metal affinity, (1) and (2) were applied to photo-oxidation of alcohols and mandelate. (1) rapidly photo-oxidized alcohols in the presence of Mg(II) and Zn(II): the rate augmentation corresponds to 16-18 fold. (2) could photo-oxidize PhCH(OH)COO-K+ but only slightly PhCH(OH)COO-NMe4+: the rate difference amounts to 110-fold. Thus, the photo-oxidizability of these modified flavins can be markedly improved through complexation with metal ions.

本文言語英語
ページ(範囲)5295-5298
ページ数4
ジャーナルTetrahedron Letters
25
46
DOI
出版ステータス出版済み - 1984
外部発表はい

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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