Light-mediated oxidation of alcohols and mandelate by flavin-metal complexes

Seiji Shinkai, Hideki Nakao, Kaori Ueda, Osamu Manabe

研究成果: ジャーナルへの寄稿記事

10 引用 (Scopus)

抄録

New flavins with metal affinity, (1) and (2) were applied to photo-oxidation of alcohols and mandelate. (1) rapidly photo-oxidized alcohols in the presence of Mg(II) and Zn(II): the rate augmentation corresponds to 16-18 fold. (2) could photo-oxidize PhCH(OH)COO-K+ but only slightly PhCH(OH)COO-NMe4 +: the rate difference amounts to 110-fold. Thus, the photo-oxidizability of these modified flavins can be markedly improved through complexation with metal ions.

元の言語英語
ページ(範囲)5295-5298
ページ数4
ジャーナルTetrahedron Letters
25
発行部数46
DOI
出版物ステータス出版済み - 1 1 1984
外部発表Yes

Fingerprint

Flavins
Coordination Complexes
Metals
Alcohols
Light
Oxidation
Photooxidation
Complexation
Metal ions
Ions
carboxyl radical
4,6-dinitro-o-cresol

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

これを引用

Light-mediated oxidation of alcohols and mandelate by flavin-metal complexes. / Shinkai, Seiji; Nakao, Hideki; Ueda, Kaori; Manabe, Osamu.

:: Tetrahedron Letters, 巻 25, 番号 46, 01.01.1984, p. 5295-5298.

研究成果: ジャーナルへの寄稿記事

Shinkai, Seiji ; Nakao, Hideki ; Ueda, Kaori ; Manabe, Osamu. / Light-mediated oxidation of alcohols and mandelate by flavin-metal complexes. :: Tetrahedron Letters. 1984 ; 巻 25, 番号 46. pp. 5295-5298.
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