Liquid crystalline microspheres of azobenzene amphiphiles formed by thermally induced pH changes in binary water-hydrolytic ionic liquid media

Tejwant Singh Kang, Masa-Aki Morikawa, Nobuo Kimizuka

研究成果: ジャーナルへの寄稿記事

抄録

Anionic azobenzene-containing bilayered membranes dispersed in binary water-ionic liquid (IL) media undergo proton-responsive transformation into liquid crystalline microspheres (LCMs). This transformation was induced by protons released by the heat-induced hydrolysis of tetrafluoroborate ions in the ILs. This work demonstrates the first beneficial use of hydrolysis-susceptible ILs in chemistry.

元の言語英語
ページ(範囲)5459-5462
ページ数4
ジャーナルChemical Communications
55
発行部数38
DOI
出版物ステータス出版済み - 1 1 2019

Fingerprint

Ionic Liquids
Amphiphiles
Azobenzene
Microspheres
Ionic liquids
Protons
Hydrolysis
Crystalline materials
Water
Liquids
Ions
Membranes
azobenzene
Hot Temperature

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

これを引用

@article{c21438c04bf04ef5a95c1c11b2f10467,
title = "Liquid crystalline microspheres of azobenzene amphiphiles formed by thermally induced pH changes in binary water-hydrolytic ionic liquid media",
abstract = "Anionic azobenzene-containing bilayered membranes dispersed in binary water-ionic liquid (IL) media undergo proton-responsive transformation into liquid crystalline microspheres (LCMs). This transformation was induced by protons released by the heat-induced hydrolysis of tetrafluoroborate ions in the ILs. This work demonstrates the first beneficial use of hydrolysis-susceptible ILs in chemistry.",
author = "Kang, {Tejwant Singh} and Masa-Aki Morikawa and Nobuo Kimizuka",
year = "2019",
month = "1",
day = "1",
doi = "10.1039/c9cc01731c",
language = "English",
volume = "55",
pages = "5459--5462",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "38",

}

TY - JOUR

T1 - Liquid crystalline microspheres of azobenzene amphiphiles formed by thermally induced pH changes in binary water-hydrolytic ionic liquid media

AU - Kang, Tejwant Singh

AU - Morikawa, Masa-Aki

AU - Kimizuka, Nobuo

PY - 2019/1/1

Y1 - 2019/1/1

N2 - Anionic azobenzene-containing bilayered membranes dispersed in binary water-ionic liquid (IL) media undergo proton-responsive transformation into liquid crystalline microspheres (LCMs). This transformation was induced by protons released by the heat-induced hydrolysis of tetrafluoroborate ions in the ILs. This work demonstrates the first beneficial use of hydrolysis-susceptible ILs in chemistry.

AB - Anionic azobenzene-containing bilayered membranes dispersed in binary water-ionic liquid (IL) media undergo proton-responsive transformation into liquid crystalline microspheres (LCMs). This transformation was induced by protons released by the heat-induced hydrolysis of tetrafluoroborate ions in the ILs. This work demonstrates the first beneficial use of hydrolysis-susceptible ILs in chemistry.

UR - http://www.scopus.com/inward/record.url?scp=85065533412&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85065533412&partnerID=8YFLogxK

U2 - 10.1039/c9cc01731c

DO - 10.1039/c9cc01731c

M3 - Article

C2 - 30997907

AN - SCOPUS:85065533412

VL - 55

SP - 5459

EP - 5462

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 38

ER -