Li0.7NbS2: Structural effects of increased alkali metal content

Pamela A. Salyer, Marten G. Barker, Duncan H. Gregory, Martin O. Jones, Claire Wilson

研究成果: ジャーナルへの寄稿学術誌査読

2 被引用数 (Scopus)


Crystals of lithium niobium disulfide [LiyNbS2; y = 0.70 (9)] have been prepared by separated reactants metathesis (SRM) at 1073 K. Single-crystal data collected at reduced temperature [150 (2) K] indicate that the compound is isostructural with Li0.63NbS2 [Salyer, Barker, Blake, Gregory & Wilson (2003). Acta Cryst. C59, i4-i6], crystallizing in the hexagonal space group P63/mmc (No. 194). Li 0.7NbS2 shows an expansion of both the a and c lattice parameters when compared with previously reported results on Li yNbS2 intercalation compounds with y < 0.70. This provides the first single-crystal structural evidence of unit cell expansion with increasing lithium content in LiyNbS2, where y > 0.5. κ 2003 International Union of Crystallography Printed in Great Britain - all rights reserved.

ジャーナルActa Crystallographica Section E: Structure Reports Online
出版ステータス出版済み - 8月 1 2003

!!!All Science Journal Classification (ASJC) codes

  • 化学 (全般)
  • 材料科学(全般)
  • 凝縮系物理学


「Li0.7NbS2: Structural effects of increased alkali metal content」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。