Low-energy electron impact investigation of the triplet states of cyclopentanone and cyclohexanone

Kenji Furuya, Etsuji Yamamoto, Youichi Jinbou, Teiichiro Ogawa

研究成果: Contribution to journalArticle査読

10 被引用数 (Scopus)

抄録

The angle-resolved electron energy-loss spectra of cyclopentanone and cyclohexanone have been measured at an electron energy of 5 eV above the threshold and at several scattering angles of 0-90 degrees. Five triplet bands together with four singlet bands have been newly observed. INDO/S CI calculations have also been performed for the spectral assignments. The singlet bands have been assigned to S1(n, π*) and 1n → 3l(l = s, p, and d) transitions, and the triplet bands have been assigned to T1(n, π*), T2(π, π*), and 3n → 3l transitions from the comparison with the VUV absorption spectra of the cyclic ketones and the electron energy-loss spectra of acetone, which were reported earlier, and the calculated transition energies.

本文言語英語
ページ(範囲)59-64
ページ数6
ジャーナルJournal of Electron Spectroscopy and Related Phenomena
73
1
DOI
出版ステータス出版済み - 5 31 1995

All Science Journal Classification (ASJC) codes

  • 電子材料、光学材料、および磁性材料
  • 放射線
  • 原子分子物理学および光学
  • 凝縮系物理学
  • 分光学
  • 物理化学および理論化学

フィンガープリント

「Low-energy electron impact investigation of the triplet states of cyclopentanone and cyclohexanone」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル