Macrocyclic Metal Complex, [6,15-Dimethyl-5,8, 9,14,17,18-hexaazadibenzo[a, A]cyclotetradecene]nickeI(II) and It's Mono- and Disulfonic Acid Derivatives

Osamu Manabe, Takaaki Sone, Hideki Imai, Yoshiaki Matsushima, Seiji Shinkai

研究成果: Contribution to journalArticle査読

1 被引用数 (Scopus)

抄録

The templet condensation of N-acetonylidene-N′-(o-aminophenyl)hydrazine (o-NH2C6H4 NHN=CHCOCH8) in the presence of nickel acetate in the mixed solvent of pyridine and ethanol (1: 10) yielded a new macrocyclic nickel complex([6,15-dimethyl-5, 8, 9,14,17,18-hexa-azadibenzo[a, A]cyclotetradecene]nickel(]I)) [2]. Central nickel of [2] could not be removed by following the treatments which were employed for the demetalation of the tetraaza-analogue of [2] ([6, 8,15,17-tetramethyl-5, 9,14,18-tetraazadibenzo[a,A]cyclotetradecene]niekel(E)): (i) suspending [2] in 1% HCl-ethanol and (ii) dissolving [2] in cone, sulfuric acid. Sul-fonation of [2] in cone, sulfuric acid and in 20% oleum afforded mono-[2a] and disulfonic acid[2b], respectively. [2a] and [2b] dyed fibers of wool, silk, and nylon dark green shade. The fastnesses of the dyeings against washing and light were 5 and 2∼3, respectively.

本文言語英語
ページ(範囲)1154-1156
ページ数3
ジャーナルNIPPON KAGAKU KAISHI
1980
7
DOI
出版ステータス出版済み - 1980
外部発表はい

All Science Journal Classification (ASJC) codes

  • 化学 (全般)
  • 化学工学(全般)

フィンガープリント

「Macrocyclic Metal Complex, [6,15-Dimethyl-5,8, 9,14,17,18-hexaazadibenzo[a, A]cyclotetradecene]nickeI(II) and It's Mono- and Disulfonic Acid Derivatives」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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