Magnetic properties of TDAE-C60 and TDAE-C70, where TDAE is tetrakis(dimethylamino)ethylene

Kazuyoshi Tanaka, Anvar A. Zakhidov, Kazunari Yoshizawa, Kenji Okahara, Tokio Yamabe, Kyuya Yakushi, Koichi Kikuchi, Shinzo Suzuki, Isao Ikemoto, Yohji Achiba

研究成果: Contribution to journalArticle査読

128 被引用数 (Scopus)

抄録

Magnetic properties of C60 and C70 complexes with tetrakis(dimethylamino) ethylene (TDAE) have been studied based on the measurements of the Faraday-balance magnetization and the electron-spin resonance (ESR). It has been found that both TDAE-C60 and TDAE-C70 possess about one radical spin per fullerene molecule. TDAE-C60 has been confirmed to show a ferromagnetic-type transition at Tc=16.7-17.5 K. Appearance of a broad and intense ESR signal below Tc for TDAE-C60 suggests that the radical spins in the magnetically ordered state are rather localized on each C60 molecule and are ferromagnetically correlated. On the other hand, TDAE-C70 does not show ferromagnetism at temperatures above 4.5 K.

本文言語英語
ページ(範囲)7554-7559
ページ数6
ジャーナルPhysical Review B
47
12
DOI
出版ステータス出版済み - 1993
外部発表はい

All Science Journal Classification (ASJC) codes

  • 凝縮系物理学

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