Me2s-induced highly selective reduction of aldehydes in the presence of ketones involving aldehyde-selective rate enhancement: A triruthenium cluster-catalyzed hydrosilylation

Shohei Yumino, Toru Hashimoto, Atsushi Tahara, Hideo Nagashima

研究成果: Contribution to journalArticle査読

7 被引用数 (Scopus)

抄録

Addition of appropriate amounts of Me2S unusually accelerated the hydrosilylation of aldehydes catalyzed by [Ru3(CO)7(Acy)] (1, Acy: μ3235-acenaphthylene). The reduction of ketones was completely suppressed under the reaction conditions. The highly selective reduction of aldehydes in the presence of ketones was achieved via a nonconventional mechanism.

本文言語英語
ページ(範囲)1829-1831
ページ数3
ジャーナルChemistry Letters
43
12
DOI
出版ステータス出版済み - 2014

All Science Journal Classification (ASJC) codes

  • 化学 (全般)

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