### 抄録

The infinite dilution activity coefficients of octane, nonane and decane in 4-methyl-n-butylpyridinium tetrafluoroborate (C_{10}H _{16}BF_{4}N, MW=237.05) were measured by gas-liquid chromatography (GC) using the ionic liquid as stationary phase. The measurements were carried out at several temperatures between 305 and 345 K. The infinite dilution activity coefficients were affected by the flow rate of carrier gas. The infinite dilution activity coefficients were determined by extrapolating the flow rate of carrier gas to zero. The infinite dilution activity coefficients determined in this work somewhat are larger than those of the literature values because the effect of flow rate of carrier gas is not considered in the literature. The experimental results were correlated by using the ASOG which is one of the successful group contribution activity coefficient models. The group interaction parameters were determined by using the Complex method to minimize the deviation between the experimental and calculated values. The correlated results are in good agreement with the experimental results.

元の言語 | 英語 |
---|---|

ホスト出版物のタイトル | 05AIChE: 2005 AIChE Annual Meeting and Fall Showcase, Conference Proceedings |

ページ | 2064 |

ページ数 | 1 |

出版物ステータス | 出版済み - 2005 |

イベント | 05AIChE: 2005 AIChE Annual Meeting and Fall Showcase - Cincinnati, OH, 米国 継続期間: 10 30 2005 → 11 4 2005 |

### その他

その他 | 05AIChE: 2005 AIChE Annual Meeting and Fall Showcase |
---|---|

国 | 米国 |

市 | Cincinnati, OH |

期間 | 10/30/05 → 11/4/05 |

### Fingerprint

### All Science Journal Classification (ASJC) codes

- Engineering(all)

### これを引用

*05AIChE: 2005 AIChE Annual Meeting and Fall Showcase, Conference Proceedings*(pp. 2064)

**Measurement of infinite dilution activity coefficients of alkanes in ionic liquid using gas-liquid chromatography.** / Inoue, Go; Yasutake, Munehiro; Iwai, Yoshio; Honda, Katsumi; Arai, Yasuhiko.

研究成果: 著書/レポートタイプへの貢献 › 会議での発言

*05AIChE: 2005 AIChE Annual Meeting and Fall Showcase, Conference Proceedings.*pp. 2064, 05AIChE: 2005 AIChE Annual Meeting and Fall Showcase, Cincinnati, OH, 米国, 10/30/05.

}

TY - GEN

T1 - Measurement of infinite dilution activity coefficients of alkanes in ionic liquid using gas-liquid chromatography

AU - Inoue, Go

AU - Yasutake, Munehiro

AU - Iwai, Yoshio

AU - Honda, Katsumi

AU - Arai, Yasuhiko

PY - 2005

Y1 - 2005

N2 - The infinite dilution activity coefficients of octane, nonane and decane in 4-methyl-n-butylpyridinium tetrafluoroborate (C10H 16BF4N, MW=237.05) were measured by gas-liquid chromatography (GC) using the ionic liquid as stationary phase. The measurements were carried out at several temperatures between 305 and 345 K. The infinite dilution activity coefficients were affected by the flow rate of carrier gas. The infinite dilution activity coefficients were determined by extrapolating the flow rate of carrier gas to zero. The infinite dilution activity coefficients determined in this work somewhat are larger than those of the literature values because the effect of flow rate of carrier gas is not considered in the literature. The experimental results were correlated by using the ASOG which is one of the successful group contribution activity coefficient models. The group interaction parameters were determined by using the Complex method to minimize the deviation between the experimental and calculated values. The correlated results are in good agreement with the experimental results.

AB - The infinite dilution activity coefficients of octane, nonane and decane in 4-methyl-n-butylpyridinium tetrafluoroborate (C10H 16BF4N, MW=237.05) were measured by gas-liquid chromatography (GC) using the ionic liquid as stationary phase. The measurements were carried out at several temperatures between 305 and 345 K. The infinite dilution activity coefficients were affected by the flow rate of carrier gas. The infinite dilution activity coefficients were determined by extrapolating the flow rate of carrier gas to zero. The infinite dilution activity coefficients determined in this work somewhat are larger than those of the literature values because the effect of flow rate of carrier gas is not considered in the literature. The experimental results were correlated by using the ASOG which is one of the successful group contribution activity coefficient models. The group interaction parameters were determined by using the Complex method to minimize the deviation between the experimental and calculated values. The correlated results are in good agreement with the experimental results.

UR - http://www.scopus.com/inward/record.url?scp=33645576980&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33645576980&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:33645576980

SP - 2064

BT - 05AIChE: 2005 AIChE Annual Meeting and Fall Showcase, Conference Proceedings

ER -