Mesophase pitch catalytically prepared from anthracene with HF/BF3

Isao Mochida, Kiyoyuki Shimizu, Yozo Korai, Yukio Sakai, Susumu Fujiyama, Hiroshi Toshima, Takashi Hono

研究成果: Contribution to journalArticle査読

76 被引用数 (Scopus)

抄録

Structure and properties of mesophase pitches prepared catalytically from anthracene by the aid of HF/BF3 were studied to reveal the influences of starting aromatic hydrocarbons. In comparison to naphthalene mesophase pitch, the anthracene pitch exhibited higher yield and slightly higher softening point under milder conditions of preparation. More naphthenic and aryl-aryl bonds with fewer methyl groups were characteristic of the anthracene pitch. Such characterizations are ascribed to the high reactivity of 9,10 positions in the anthracene ring. Although difficulty of spinning reduced the tensile strength of its resultant carbon fiber, its larger molecular units provided higher young modulus, especially at lower graphitization temperature. Lower spinning viscosity was found to give higher modulus of the carbon fiber from the same mesophase pitch at the same graphitization temperature. Molecular alignment at the spinning is briefly discussed.

本文言語英語
ページ(範囲)55-61
ページ数7
ジャーナルCarbon
30
1
DOI
出版ステータス出版済み - 1992

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)

フィンガープリント 「Mesophase pitch catalytically prepared from anthracene with HF/BF<sub>3</sub>」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル