Mesoscopic Heterogeneity in Pore Size of Supramolecular Networks

Yuji Matsumoto, Atsuomi Shundo, Masashi Ohno, Nobutomo Tsuruzoe, Masahiro Goto, Keiji Tanaka

研究成果: ジャーナルへの寄稿記事

2 引用 (Scopus)

抄録

There has been a considerable interest in developing new types of gels based on a network of fibrous aggregate composed of low molecular weight gelators, also known as supramolecular gels (SMGs). Unlike conventional polymer gels with chemical cross-linking, the network formation in SMGs does not involve any covalent bonds. Thus, the network in SMGs has been often regarded as homogenous or less heterogeneous in comparison with that in chemically cross-linked polymer gels. In this study, we have experimentally verified the existence of the network heterogeneity even in SMGs. The thermal motion of probe particles in SMGs, which were prepared from aqueous dispersions of gelators having a different number of peptide residues, PalGH, PalG2H, and PalG3H, was tracked. The gels were spatially heterogeneous in terms of the network pore size, as evidenced by the variation in the particle motion depending on the location, at which a particle existed. With varying particle size, it was found that the characteristic length scale of the heterogeneity was in the order of (sub)micrometers and was smaller in the order of the PalG2H, PalG3H, and PalGH gels.

元の言語英語
ページ(範囲)7503-7508
ページ数6
ジャーナルLangmuir
34
発行部数25
DOI
出版物ステータス出版済み - 6 26 2018

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Pore size
Gels
gels
porosity
Polymers
Covalent bonds
covalent bonds
polymers
particle motion
low molecular weights
Dispersions
Peptides
Particles (particulate matter)
peptides
micrometers
Molecular weight
Particle size
probes

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

これを引用

Mesoscopic Heterogeneity in Pore Size of Supramolecular Networks. / Matsumoto, Yuji; Shundo, Atsuomi; Ohno, Masashi; Tsuruzoe, Nobutomo; Goto, Masahiro; Tanaka, Keiji.

:: Langmuir, 巻 34, 番号 25, 26.06.2018, p. 7503-7508.

研究成果: ジャーナルへの寄稿記事

Matsumoto, Yuji ; Shundo, Atsuomi ; Ohno, Masashi ; Tsuruzoe, Nobutomo ; Goto, Masahiro ; Tanaka, Keiji. / Mesoscopic Heterogeneity in Pore Size of Supramolecular Networks. :: Langmuir. 2018 ; 巻 34, 番号 25. pp. 7503-7508.
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