Metal catalyzed synthetic reactions via aerobic oxidation as a key step

Mitsuru Shindo, Kenji Matsumoto

研究成果: Chapter in Book/Report/Conference proceedingChapter

5 被引用数 (Scopus)

抄録

New aerobic oxidative metal catalyzed synthetic reactions are described: The Cu(II) complex catalyzed the acylation of thioester in Wittig lactonization under neutral conditions and the dissymmetrization of symmetric dithiomalonates via selective monoacylation. The key step in this reaction was the formation of an acylketene, the stability of which would contribute to selectivity. The aerobic Rh/C-catalyzed oxidative homo- and cross-coupling of aryl amines was developed. The coupling reactions afforded symmetrical and nonsymmetrical biaryl amines in excellent yields. These reactions provide a mild, operationally simple, and efficient approach for the synthesis of biaryls which are important to pharmaceutical and materials chemistry.

本文言語英語
ホスト出版物のタイトルNew Horizons of Process Chemistry
ホスト出版物のサブタイトルScalable Reactions and Technologies
出版社Springer Singapore
ページ11-27
ページ数17
ISBN(電子版)9789811034213
ISBN(印刷版)9789811034206
DOI
出版ステータス出版済み - 1 1 2017

All Science Journal Classification (ASJC) codes

  • 化学 (全般)
  • 化学工学(全般)
  • 医学(全般)
  • 工学(全般)
  • 農業および生物科学(全般)

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