Metal complexes-catalyzed hydrolysis and alcoholysis of organic substrates and their application to kinetic resolution

Makoto Tokunaga, Hiroshi Aoyama, Junya Kiyosu, Yuki Shirogane, Tetsuo Iwasawa, Yasushi Obora, Yasushi Tsuji

研究成果: Contribution to journalArticle

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抜粋

Metal complexes-catalyzed hydrolysis and alcoholysis of organic substrates such as alkenyl esters, alkenyl ethers, and azlactones (oxazol-5(4H)-ones) are described. These reactions were applied for kinetic resolution of chiral compounds and high selectivities were achieved with vinyl ethers of 2-substituted cyclohexanols, 1,1′-bi-2-naphthols, 1,1′-bi-2-phenols, and 4,4-disubstituted azlactones. Oxidative carbon-carbon bond cleavage reactions, which were found in the course of the study of asymmetric hydrolysis were also described.

元の言語英語
ページ(範囲)472-480
ページ数9
ジャーナルJournal of Organometallic Chemistry
692
発行部数1-3
DOI
出版物ステータス出版済み - 1 1 2007
外部発表Yes

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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