Metalation chemistry of meso-aryl-substituted expanded porphyrins

Soji Shimizu, Atsuhiro Osuka

研究成果: Contribution to journalShort survey査読

113 被引用数 (Scopus)

抄録

meso-Aryl-substituted expanded porphyrins are structural analogues of meso-aryl-substituted porphyrins. They exhibit rich and novel coordination behaviors, including multi-metal chelation due to the large cavities, spin-spin interaction arising from the proximity of metal centers, and large changes in their structural and electrochemical properties upon metalation. The recent discovery of a facile, one-pot synthesis of a series of meso-aryl-substituted expanded porphyrins enables us to investigate their metal-complexation chemistry. The aim of this Microreview is to highlight recent progress in the synthesis and characterization of metal complexes of meso-aryl-substituted expanded porphyrins.

本文言語英語
ページ(範囲)1319-1335
ページ数17
ジャーナルEuropean Journal of Inorganic Chemistry
7
DOI
出版ステータス出版済み - 4 3 2006
外部発表はい

All Science Journal Classification (ASJC) codes

  • 無機化学

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