Metallogrid Single-Molecule Magnet: Solvent-Induced Nuclearity Transformation and Magnetic Hysteresis at 16 K

Wei Huang; Fu Xing Shen; Shu Qi Wu; Li Liu; Dayu Wu; Zhe Zheng; Jun Xu; Ming Zhang; Xing Cai Huang; Jun Jiang; Feifei Pan; Yao Li; Kun Zhu; Osamu Sato

doi:10.1021/acs.inorgchem.6b00500

Metallogrid Single-Molecule Magnet: Solvent-Induced Nuclearity Transformation and Magnetic Hysteresis at 16 K

Wei Huang, Fu Xing Shen, Shu Qi Wu, Li Liu, Dayu Wu, Zhe Zheng, Jun Xu, Ming Zhang, Xing Cai Huang, Jun Jiang, Feifei Pan, Yao Li, Kun Zhu, Osamu Sato

物質基盤化学部門

研究成果: Contribution to journal › Article › 査読

53 被引用数 (Scopus)

抄録

Structural assembly and reversible transformation between a metallogrid Dy₄ SMM (2) and its fragment Dy₂ (1) were established in the different solvent media. The zero-field magnetization relaxation was slowed for dysprosium metallogrid (2) with relaxation barrier of U_eff = 61.3 K when compared to Dy₂ (1). Both magnetic dilution and application of a moderate magnetic field suppress ground-state quantum tunneling of magnetization and result in an enhanced U_eff of 119.9 and 96.7 K for 2, respectively. Interestingly, the lanthanide metallogrid complex (2) exhibits magnetic hysteresis loop even up to 16 K at a given field sweep rate of 500 Oe/s.

本文言語	英語
ページ（範囲）	5476-5484
ページ数	9
ジャーナル	Inorganic chemistry
巻	55
号	11
DOI	https://doi.org/10.1021/acs.inorgchem.6b00500
出版ステータス	出版済み - 6 6 2016

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

文献へのアクセス

10.1021/acs.inorgchem.6b00500

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引用スタイル

Metallogrid Single-Molecule Magnet : Solvent-Induced Nuclearity Transformation and Magnetic Hysteresis at 16 K. / Huang, Wei; Shen, Fu Xing; Wu, Shu Qi; Liu, Li; Wu, Dayu; Zheng, Zhe; Xu, Jun; Zhang, Ming; Huang, Xing Cai; Jiang, Jun; Pan, Feifei; Li, Yao; Zhu, Kun; Sato, Osamu.

In: Inorganic chemistry, Vol. 55, No. 11, 06.06.2016, p. 5476-5484.

研究成果: Contribution to journal › Article › 査読

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abstract = "Structural assembly and reversible transformation between a metallogrid Dy4 SMM (2) and its fragment Dy2 (1) were established in the different solvent media. The zero-field magnetization relaxation was slowed for dysprosium metallogrid (2) with relaxation barrier of Ueff = 61.3 K when compared to Dy2 (1). Both magnetic dilution and application of a moderate magnetic field suppress ground-state quantum tunneling of magnetization and result in an enhanced Ueff of 119.9 and 96.7 K for 2, respectively. Interestingly, the lanthanide metallogrid complex (2) exhibits magnetic hysteresis loop even up to 16 K at a given field sweep rate of 500 Oe/s.",

author = "Wei Huang and Shen, {Fu Xing} and Wu, {Shu Qi} and Li Liu and Dayu Wu and Zhe Zheng and Jun Xu and Ming Zhang and Huang, {Xing Cai} and Jun Jiang and Feifei Pan and Yao Li and Kun Zhu and Osamu Sato",

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AU - Huang, Wei

AU - Shen, Fu Xing

AU - Wu, Shu Qi

AU - Liu, Li

AU - Wu, Dayu

AU - Zheng, Zhe

AU - Xu, Jun

AU - Zhang, Ming

AU - Huang, Xing Cai

AU - Jiang, Jun

AU - Pan, Feifei

AU - Li, Yao

AU - Zhu, Kun

AU - Sato, Osamu

PY - 2016/6/6

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AB - Structural assembly and reversible transformation between a metallogrid Dy4 SMM (2) and its fragment Dy2 (1) were established in the different solvent media. The zero-field magnetization relaxation was slowed for dysprosium metallogrid (2) with relaxation barrier of Ueff = 61.3 K when compared to Dy2 (1). Both magnetic dilution and application of a moderate magnetic field suppress ground-state quantum tunneling of magnetization and result in an enhanced Ueff of 119.9 and 96.7 K for 2, respectively. Interestingly, the lanthanide metallogrid complex (2) exhibits magnetic hysteresis loop even up to 16 K at a given field sweep rate of 500 Oe/s.

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