@article{fd1567cc7bc5471a9f8dea7c9d6df78a,
title = "Metallogrid Single-Molecule Magnet: Solvent-Induced Nuclearity Transformation and Magnetic Hysteresis at 16 K",
abstract = "Structural assembly and reversible transformation between a metallogrid Dy4 SMM (2) and its fragment Dy2 (1) were established in the different solvent media. The zero-field magnetization relaxation was slowed for dysprosium metallogrid (2) with relaxation barrier of Ueff = 61.3 K when compared to Dy2 (1). Both magnetic dilution and application of a moderate magnetic field suppress ground-state quantum tunneling of magnetization and result in an enhanced Ueff of 119.9 and 96.7 K for 2, respectively. Interestingly, the lanthanide metallogrid complex (2) exhibits magnetic hysteresis loop even up to 16 K at a given field sweep rate of 500 Oe/s.",
author = "Wei Huang and Shen, {Fu Xing} and Wu, {Shu Qi} and Li Liu and Dayu Wu and Zhe Zheng and Jun Xu and Ming Zhang and Huang, {Xing Cai} and Jun Jiang and Feifei Pan and Yao Li and Kun Zhu and Osamu Sato",
note = "Funding Information: We are thankful for financial support by the Priority Academic Program Development of Jiangsu Higher Education Institutions. This experimental work is financially supported by the National Natural Science Foundation of China (Grant Nos. 21471023 and 21371010) and sponsored by Jiangsu Provincial QingLan Project. The magnetic hysteresis was undertaken on a conventional SQUID VSM apparatus in SKLCC of Nanjing University, China. Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",
year = "2016",
month = jun,
day = "6",
doi = "10.1021/acs.inorgchem.6b00500",
language = "English",
volume = "55",
pages = "5476--5484",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "11",
}