抄録
Over the past decade, zeolites (microporous aluminosilicate minerals) have been gaining significant popularity due to their broad applications in catalysis including the dream reaction of selective oxidation (hydroxylation) of methane to methanol at low temperature. In this review, we outline the current main challenges in the development of Fe-, Cu-, Co- and Ni-exchanged zeolites for methane hydroxylation and summarize key findings that have been reported in both spectroscopy and computational studies. Also, using density functional theory (DFT) calculations, we calculate energy diagrams of methane hydroxylation over various structures of metal-oxo active sites in zeolites and discuss some key points that can be improved for achieving higher reactivity. Short outlooks on the future research opportunities are also discussed.
| 元の言語 | 英語 |
|---|---|
| ページ（範囲） | 1744-1768 |
| ページ数 | 25 |
| ジャーナル | Catalysis Science and Technology |
| 巻 | 9 |
| 発行部数 | 8 |
| DOI | |
| 出版物ステータス | 出版済み - 1 1 2019 |
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All Science Journal Classification (ASJC) codes
- Catalysis
これを引用
Methane selective oxidation to methanol by metal-exchanged zeolites : A review of active sites and their reactivity. / Mahyuddin, Muhammad Haris; Shiota, Yoshihito; Yoshizawa, Kazunari.
：: Catalysis Science and Technology, 巻 9, 番号 8, 01.01.2019, p. 1744-1768.研究成果: ジャーナルへの寄稿 › 評論記事
}
TY - JOUR
T1 - Methane selective oxidation to methanol by metal-exchanged zeolites
T2 - A review of active sites and their reactivity
AU - Mahyuddin, Muhammad Haris
AU - Shiota, Yoshihito
AU - Yoshizawa, Kazunari
PY - 2019/1/1
Y1 - 2019/1/1
N2 - Over the past decade, zeolites (microporous aluminosilicate minerals) have been gaining significant popularity due to their broad applications in catalysis including the dream reaction of selective oxidation (hydroxylation) of methane to methanol at low temperature. In this review, we outline the current main challenges in the development of Fe-, Cu-, Co- and Ni-exchanged zeolites for methane hydroxylation and summarize key findings that have been reported in both spectroscopy and computational studies. Also, using density functional theory (DFT) calculations, we calculate energy diagrams of methane hydroxylation over various structures of metal-oxo active sites in zeolites and discuss some key points that can be improved for achieving higher reactivity. Short outlooks on the future research opportunities are also discussed.
AB - Over the past decade, zeolites (microporous aluminosilicate minerals) have been gaining significant popularity due to their broad applications in catalysis including the dream reaction of selective oxidation (hydroxylation) of methane to methanol at low temperature. In this review, we outline the current main challenges in the development of Fe-, Cu-, Co- and Ni-exchanged zeolites for methane hydroxylation and summarize key findings that have been reported in both spectroscopy and computational studies. Also, using density functional theory (DFT) calculations, we calculate energy diagrams of methane hydroxylation over various structures of metal-oxo active sites in zeolites and discuss some key points that can be improved for achieving higher reactivity. Short outlooks on the future research opportunities are also discussed.
UR - http://www.scopus.com/inward/record.url?scp=85064504819&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85064504819&partnerID=8YFLogxK
U2 - 10.1039/c8cy02414f
DO - 10.1039/c8cy02414f
M3 - Review article
AN - SCOPUS:85064504819
VL - 9
SP - 1744
EP - 1768
JO - Catalysis Science and Technology
JF - Catalysis Science and Technology
SN - 2044-4753
IS - 8
ER -