Methane selective oxidation to methanol by metal-exchanged zeolites

A review of active sites and their reactivity

Muhammad Haris Mahyuddin, Yoshihito Shiota, Kazunari Yoshizawa

研究成果: ジャーナルへの寄稿評論記事

抄録

Over the past decade, zeolites (microporous aluminosilicate minerals) have been gaining significant popularity due to their broad applications in catalysis including the dream reaction of selective oxidation (hydroxylation) of methane to methanol at low temperature. In this review, we outline the current main challenges in the development of Fe-, Cu-, Co- and Ni-exchanged zeolites for methane hydroxylation and summarize key findings that have been reported in both spectroscopy and computational studies. Also, using density functional theory (DFT) calculations, we calculate energy diagrams of methane hydroxylation over various structures of metal-oxo active sites in zeolites and discuss some key points that can be improved for achieving higher reactivity. Short outlooks on the future research opportunities are also discussed.

元の言語英語
ページ(範囲)1744-1768
ページ数25
ジャーナルCatalysis Science and Technology
9
発行部数8
DOI
出版物ステータス出版済み - 1 1 2019

Fingerprint

Zeolites
Hydroxylation
Methane
Methanol
Metals
Oxidation
Aluminosilicates
Catalysis
Density functional theory
Minerals
Spectroscopy
Temperature

All Science Journal Classification (ASJC) codes

  • Catalysis

これを引用

Methane selective oxidation to methanol by metal-exchanged zeolites : A review of active sites and their reactivity. / Mahyuddin, Muhammad Haris; Shiota, Yoshihito; Yoshizawa, Kazunari.

:: Catalysis Science and Technology, 巻 9, 番号 8, 01.01.2019, p. 1744-1768.

研究成果: ジャーナルへの寄稿評論記事

@article{bab79bebbf8c4661bce9789cce18366f,
title = "Methane selective oxidation to methanol by metal-exchanged zeolites: A review of active sites and their reactivity",
abstract = "Over the past decade, zeolites (microporous aluminosilicate minerals) have been gaining significant popularity due to their broad applications in catalysis including the dream reaction of selective oxidation (hydroxylation) of methane to methanol at low temperature. In this review, we outline the current main challenges in the development of Fe-, Cu-, Co- and Ni-exchanged zeolites for methane hydroxylation and summarize key findings that have been reported in both spectroscopy and computational studies. Also, using density functional theory (DFT) calculations, we calculate energy diagrams of methane hydroxylation over various structures of metal-oxo active sites in zeolites and discuss some key points that can be improved for achieving higher reactivity. Short outlooks on the future research opportunities are also discussed.",
author = "Mahyuddin, {Muhammad Haris} and Yoshihito Shiota and Kazunari Yoshizawa",
year = "2019",
month = "1",
day = "1",
doi = "10.1039/c8cy02414f",
language = "English",
volume = "9",
pages = "1744--1768",
journal = "Catalysis Science and Technology",
issn = "2044-4753",
publisher = "Royal Society of Chemistry",
number = "8",

}

TY - JOUR

T1 - Methane selective oxidation to methanol by metal-exchanged zeolites

T2 - A review of active sites and their reactivity

AU - Mahyuddin, Muhammad Haris

AU - Shiota, Yoshihito

AU - Yoshizawa, Kazunari

PY - 2019/1/1

Y1 - 2019/1/1

N2 - Over the past decade, zeolites (microporous aluminosilicate minerals) have been gaining significant popularity due to their broad applications in catalysis including the dream reaction of selective oxidation (hydroxylation) of methane to methanol at low temperature. In this review, we outline the current main challenges in the development of Fe-, Cu-, Co- and Ni-exchanged zeolites for methane hydroxylation and summarize key findings that have been reported in both spectroscopy and computational studies. Also, using density functional theory (DFT) calculations, we calculate energy diagrams of methane hydroxylation over various structures of metal-oxo active sites in zeolites and discuss some key points that can be improved for achieving higher reactivity. Short outlooks on the future research opportunities are also discussed.

AB - Over the past decade, zeolites (microporous aluminosilicate minerals) have been gaining significant popularity due to their broad applications in catalysis including the dream reaction of selective oxidation (hydroxylation) of methane to methanol at low temperature. In this review, we outline the current main challenges in the development of Fe-, Cu-, Co- and Ni-exchanged zeolites for methane hydroxylation and summarize key findings that have been reported in both spectroscopy and computational studies. Also, using density functional theory (DFT) calculations, we calculate energy diagrams of methane hydroxylation over various structures of metal-oxo active sites in zeolites and discuss some key points that can be improved for achieving higher reactivity. Short outlooks on the future research opportunities are also discussed.

UR - http://www.scopus.com/inward/record.url?scp=85064504819&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85064504819&partnerID=8YFLogxK

U2 - 10.1039/c8cy02414f

DO - 10.1039/c8cy02414f

M3 - Review article

VL - 9

SP - 1744

EP - 1768

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

SN - 2044-4753

IS - 8

ER -