TY - JOUR
T1 - Method for a convenient and efficient synthesis of amino acid acrylic monomers with zwitterionic structure
AU - Nagaoka, Shoji
AU - Shundo, Atsuomi
AU - Satoh, Takao
AU - Nagira, Kazuhiko
AU - Kishi, Ryoich
AU - Ueno, Katsuhiko
AU - Iio, Kokoro
AU - Ihara, Hirotaka
PY - 2005
Y1 - 2005
N2 - Ampholyte monomers with zwitterionic moiety derived from α-amino acid, that is, L-lysine and L-serine, were obtained using a method in which their copper complexes could be produced in simple steps. The N-acryloylation of L-lysine and L-serine was carried out by reaction between their copper complexes and acryloyl chloride. Specifically, the removal of copper from the copper complex of acryloyl amino acid through the use of 8-hydroxyquinoline as an organic chelate precipitant increased the yield of the ampholyte monomers with zwitterionic moiety. These syntheses were easily carried out in a three-step procedure.
AB - Ampholyte monomers with zwitterionic moiety derived from α-amino acid, that is, L-lysine and L-serine, were obtained using a method in which their copper complexes could be produced in simple steps. The N-acryloylation of L-lysine and L-serine was carried out by reaction between their copper complexes and acryloyl chloride. Specifically, the removal of copper from the copper complex of acryloyl amino acid through the use of 8-hydroxyquinoline as an organic chelate precipitant increased the yield of the ampholyte monomers with zwitterionic moiety. These syntheses were easily carried out in a three-step procedure.
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U2 - 10.1080/00397910500212932
DO - 10.1080/00397910500212932
M3 - Article
AN - SCOPUS:26044435954
VL - 35
SP - 2529
EP - 2534
JO - Synthetic Communications
JF - Synthetic Communications
SN - 0039-7911
IS - 19
ER -