Michael addition of methyl 2-(trimethysily)propenoate with organomagnesiums or organolithiums leading to 1:1 and / or 2:1 adducts and subsequent peterson olefination by condensation with carbonyl compounds

J. Tanaka, S. Kanemasa, Y. Ninomiya, O. Tsuge

研究成果: Contribution to journalArticle査読

9 被引用数 (Scopus)

抄録

Michael addition of methyl 2-(trimethylsilyl)propenoate with organomagnesiums or organolithiums leads to 1:1 and/or 1:2 adduct anions which can be utilized in the subsequent step of Peterson olefination with carbonyl compounds. The 1:1/1:2 ratio depends upon the nature of donor molecules, the reaction conditions such as reaction temperature, polarity of solvent, and rate of addition of the acceptor molecule. Use of acceptors in excess results in the selective formation of 1:2 and/or 1:3 adducts.

本文言語英語
ページ(範囲)466-475
ページ数10
ジャーナルBulletin of the Chemical Society of Japan
63
2
DOI
出版ステータス出版済み - 1990

All Science Journal Classification (ASJC) codes

  • 化学 (全般)

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「Michael addition of methyl 2-(trimethysily)propenoate with organomagnesiums or organolithiums leading to 1:1 and / or 2:1 adducts and subsequent peterson olefination by condensation with carbonyl compounds」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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