[Mn4III3-O)2(μ-O 2CMe)7(2,2′-bipyridine)2]ClO4

Tsuyoshi Tamane, Taro Tsubomura, Ken Sakai

研究成果: Contribution to journalArticle査読

4 被引用数 (Scopus)

抄録

The anhydrous form of a known tetramanganese cluster, which was previously isolated in its trihydrate form, has been prepared from a different starting material. The new complex, bis(μ3-oxo)-1:2:4κ3O;2:3:4κ 3O-heptakis(μ-acetato)-1:2κ 4O:O′;1:4κ:2O:O′;2:3κ 2O:O′;2:4κ2-O:O′;3:4κ 4O:O′-bis(2,2′-bipyridine)-1κ 2N,N′3κ2N,N′-tetramanganese perchlorate, [Mn4(O)2(C2H3O2) 7 (C10H8N2)2]ClO4, crystallizes in the monoclinic space group C2/c, in a higher symmetry compared to the previous form. A crystallographic twofold axis passes through the centre of the molecule. The fundamental structure of the complex clearly resembles that of the form already reported.

本文言語英語
ページ(範囲)777-779
ページ数3
ジャーナルActa Crystallographica Section C: Crystal Structure Communications
52
4
DOI
出版ステータス出版済み - 4 15 1996
外部発表はい

All Science Journal Classification (ASJC) codes

  • Biochemistry, Genetics and Molecular Biology(all)

フィンガープリント 「[Mn<sub>4</sub><sup>III</sup>(μ<sub>3</sub>-O)<sub>2</sub>(μ-O <sub>2</sub>CMe)<sub>7</sub>(2,2′-bipyridine)<sub>2</sub>]ClO<sub>4</sub>」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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