抄録
The anhydrous form of a known tetramanganese cluster, which was previously isolated in its trihydrate form, has been prepared from a different starting material. The new complex, bis(μ3-oxo)-1:2:4κ3O;2:3:4κ 3O-heptakis(μ-acetato)-1:2κ 4O:O′;1:4κ:2O:O′;2:3κ 2O:O′;2:4κ2-O:O′;3:4κ 4O:O′-bis(2,2′-bipyridine)-1κ 2N,N′3κ2N,N′-tetramanganese perchlorate, [Mn4(O)2(C2H3O2) 7 (C10H8N2)2]ClO4, crystallizes in the monoclinic space group C2/c, in a higher symmetry compared to the previous form. A crystallographic twofold axis passes through the centre of the molecule. The fundamental structure of the complex clearly resembles that of the form already reported.
| 元の言語 | 英語 |
|---|---|
| ページ（範囲） | 777-779 |
| ページ数 | 3 |
| ジャーナル | Acta Crystallographica Section C: Crystal Structure Communications |
| 巻 | 52 |
| 発行部数 | 4 |
| DOI | |
| 出版物ステータス | 出版済み - 4 15 1996 |
| 外部発表 | Yes |
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All Science Journal Classification (ASJC) codes
- Biochemistry, Genetics and Molecular Biology(all)
これを引用
[Mn4III(μ3-O)2(μ-O 2CMe)7(2,2′-bipyridine)2]ClO4. / Tamane, Tsuyoshi; Tsubomura, Taro; Sakai, Ken.
：: Acta Crystallographica Section C: Crystal Structure Communications, 巻 52, 番号 4, 15.04.1996, p. 777-779.研究成果: ジャーナルへの寄稿 › 記事
}
TY - JOUR
T1 - [Mn4III(μ3-O)2(μ-O 2CMe)7(2,2′-bipyridine)2]ClO4
AU - Tamane, Tsuyoshi
AU - Tsubomura, Taro
AU - Sakai, Ken
PY - 1996/4/15
Y1 - 1996/4/15
N2 - The anhydrous form of a known tetramanganese cluster, which was previously isolated in its trihydrate form, has been prepared from a different starting material. The new complex, bis(μ3-oxo)-1:2:4κ3O;2:3:4κ 3O-heptakis(μ-acetato)-1:2κ 4O:O′;1:4κ:2O:O′;2:3κ 2O:O′;2:4κ2-O:O′;3:4κ 4O:O′-bis(2,2′-bipyridine)-1κ 2N,N′3κ2N,N′-tetramanganese perchlorate, [Mn4(O)2(C2H3O2) 7 (C10H8N2)2]ClO4, crystallizes in the monoclinic space group C2/c, in a higher symmetry compared to the previous form. A crystallographic twofold axis passes through the centre of the molecule. The fundamental structure of the complex clearly resembles that of the form already reported.
AB - The anhydrous form of a known tetramanganese cluster, which was previously isolated in its trihydrate form, has been prepared from a different starting material. The new complex, bis(μ3-oxo)-1:2:4κ3O;2:3:4κ 3O-heptakis(μ-acetato)-1:2κ 4O:O′;1:4κ:2O:O′;2:3κ 2O:O′;2:4κ2-O:O′;3:4κ 4O:O′-bis(2,2′-bipyridine)-1κ 2N,N′3κ2N,N′-tetramanganese perchlorate, [Mn4(O)2(C2H3O2) 7 (C10H8N2)2]ClO4, crystallizes in the monoclinic space group C2/c, in a higher symmetry compared to the previous form. A crystallographic twofold axis passes through the centre of the molecule. The fundamental structure of the complex clearly resembles that of the form already reported.
UR - http://www.scopus.com/inward/record.url?scp=0030124899&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0030124899&partnerID=8YFLogxK
U2 - 10.1107/S0108270195013333
DO - 10.1107/S0108270195013333
M3 - Article
AN - SCOPUS:0030124899
VL - 52
SP - 777
EP - 779
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
IS - 4
ER -