TY - JOUR
T1 - [Mn4III(μ3-O)2(μ-O 2CMe)7(2,2′-bipyridine)2]ClO4
AU - Tamane, Tsuyoshi
AU - Tsubomura, Taro
AU - Sakai, Ken
PY - 1996/4/15
Y1 - 1996/4/15
N2 - The anhydrous form of a known tetramanganese cluster, which was previously isolated in its trihydrate form, has been prepared from a different starting material. The new complex, bis(μ3-oxo)-1:2:4κ3O;2:3:4κ 3O-heptakis(μ-acetato)-1:2κ 4O:O′;1:4κ:2O:O′;2:3κ 2O:O′;2:4κ2-O:O′;3:4κ 4O:O′-bis(2,2′-bipyridine)-1κ 2N,N′3κ2N,N′-tetramanganese perchlorate, [Mn4(O)2(C2H3O2) 7 (C10H8N2)2]ClO4, crystallizes in the monoclinic space group C2/c, in a higher symmetry compared to the previous form. A crystallographic twofold axis passes through the centre of the molecule. The fundamental structure of the complex clearly resembles that of the form already reported.
AB - The anhydrous form of a known tetramanganese cluster, which was previously isolated in its trihydrate form, has been prepared from a different starting material. The new complex, bis(μ3-oxo)-1:2:4κ3O;2:3:4κ 3O-heptakis(μ-acetato)-1:2κ 4O:O′;1:4κ:2O:O′;2:3κ 2O:O′;2:4κ2-O:O′;3:4κ 4O:O′-bis(2,2′-bipyridine)-1κ 2N,N′3κ2N,N′-tetramanganese perchlorate, [Mn4(O)2(C2H3O2) 7 (C10H8N2)2]ClO4, crystallizes in the monoclinic space group C2/c, in a higher symmetry compared to the previous form. A crystallographic twofold axis passes through the centre of the molecule. The fundamental structure of the complex clearly resembles that of the form already reported.
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U2 - 10.1107/S0108270195013333
DO - 10.1107/S0108270195013333
M3 - Article
AN - SCOPUS:0030124899
VL - 52
SP - 777
EP - 779
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
IS - 4
ER -