[Mn4III(μ3-O)2(μ-O 2CMe)7(2,2′-bipyridine)2]ClO4

Tsuyoshi Tamane; Taro Tsubomura; Ken Sakai

doi:10.1107/S0108270195013333

[Mn₄^III(μ₃-O)₂(μ-O ₂CMe)₇(2,2′-bipyridine)₂]ClO₄

Tsuyoshi Tamane, Taro Tsubomura, Ken Sakai

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

4 被引用数 (Scopus)

抄録

The anhydrous form of a known tetramanganese cluster, which was previously isolated in its trihydrate form, has been prepared from a different starting material. The new complex, bis(μ₃-oxo)-1:2:4κ³O;2:3:4κ ³O-heptakis(μ-acetato)-1:2κ ⁴O:O′;1:4κ:²O:O′;2:3κ ²O:O′;2:4κ²-O:O′;3:4κ ⁴O:O′-bis(2,2′-bipyridine)-1κ ²N,N′3κ²N,N′-tetramanganese perchlorate, [Mn₄(O)₂(C₂H₃O₂) ₇ (C₁₀H₈N₂)₂]ClO₄, crystallizes in the monoclinic space group C2/c, in a higher symmetry compared to the previous form. A crystallographic twofold axis passes through the centre of the molecule. The fundamental structure of the complex clearly resembles that of the form already reported.

本文言語	英語
ページ（範囲）	777-779
ページ数	3
ジャーナル	Acta Crystallographica Section C: Crystal Structure Communications
巻	52
号	4
DOI	https://doi.org/10.1107/S0108270195013333
出版ステータス	出版済み - 4月 15 1996
外部発表	はい

All Science Journal Classification (ASJC) codes

生化学、遺伝学、分子生物学（全般）

文献へのアクセス

10.1107/S0108270195013333

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引用スタイル

@article{77b049ed81e74cd8873dcd6df4a5bd4a,

title = "[Mn4III(μ3-O)2(μ-O 2CMe)7(2,2′-bipyridine)2]ClO4",

abstract = "The anhydrous form of a known tetramanganese cluster, which was previously isolated in its trihydrate form, has been prepared from a different starting material. The new complex, bis(μ3-oxo)-1:2:4κ3O;2:3:4κ 3O-heptakis(μ-acetato)-1:2κ 4O:O′;1:4κ:2O:O′;2:3κ 2O:O′;2:4κ2-O:O′;3:4κ 4O:O′-bis(2,2′-bipyridine)-1κ 2N,N′3κ2N,N′-tetramanganese perchlorate, [Mn4(O)2(C2H3O2) 7 (C10H8N2)2]ClO4, crystallizes in the monoclinic space group C2/c, in a higher symmetry compared to the previous form. A crystallographic twofold axis passes through the centre of the molecule. The fundamental structure of the complex clearly resembles that of the form already reported.",

author = "Tsuyoshi Tamane and Taro Tsubomura and Ken Sakai",

year = "1996",

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T1 - [Mn4III(μ3-O)2(μ-O 2CMe)7(2,2′-bipyridine)2]ClO4

AU - Tamane, Tsuyoshi

AU - Tsubomura, Taro

AU - Sakai, Ken

PY - 1996/4/15

Y1 - 1996/4/15

N2 - The anhydrous form of a known tetramanganese cluster, which was previously isolated in its trihydrate form, has been prepared from a different starting material. The new complex, bis(μ3-oxo)-1:2:4κ3O;2:3:4κ 3O-heptakis(μ-acetato)-1:2κ 4O:O′;1:4κ:2O:O′;2:3κ 2O:O′;2:4κ2-O:O′;3:4κ 4O:O′-bis(2,2′-bipyridine)-1κ 2N,N′3κ2N,N′-tetramanganese perchlorate, [Mn4(O)2(C2H3O2) 7 (C10H8N2)2]ClO4, crystallizes in the monoclinic space group C2/c, in a higher symmetry compared to the previous form. A crystallographic twofold axis passes through the centre of the molecule. The fundamental structure of the complex clearly resembles that of the form already reported.

AB - The anhydrous form of a known tetramanganese cluster, which was previously isolated in its trihydrate form, has been prepared from a different starting material. The new complex, bis(μ3-oxo)-1:2:4κ3O;2:3:4κ 3O-heptakis(μ-acetato)-1:2κ 4O:O′;1:4κ:2O:O′;2:3κ 2O:O′;2:4κ2-O:O′;3:4κ 4O:O′-bis(2,2′-bipyridine)-1κ 2N,N′3κ2N,N′-tetramanganese perchlorate, [Mn4(O)2(C2H3O2) 7 (C10H8N2)2]ClO4, crystallizes in the monoclinic space group C2/c, in a higher symmetry compared to the previous form. A crystallographic twofold axis passes through the centre of the molecule. The fundamental structure of the complex clearly resembles that of the form already reported.

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