Modern microwave methods in solid-state inorganic materials chemistry: From fundamentals to manufacturing

Helen J. Kitchen, Simon R. Vallance, Jennifer L. Kennedy, Nuria Tapia-Ruiz, Lucia Carassiti, Andrew Harrison, A. Gavin Whittaker, Timothy D. Drysdale, Samuel W. Kingman, Duncan H. Gregory

研究成果: Contribution to journalReview article査読

231 被引用数 (Scopus)

抄録

The significant advances in the area of solid-state microwave (MW) synthesis are studied. MWs are broadly regarded as those electromagnetic waves which are situated between infrared and radio wavelengths in the electromagnetic spectrum, with wavelengths between 0.01 and 1 m, corresponding to frequencies between 0.3 and 300 GHz. MW radiation interacts directly with the reaction components, so the sample alone is heated with minimal need for energy to be expended in heating furnaces, containment materials, and the sample environment. While absorption of MWs in solid and liquid samples is frequency dependent, it is, in effect, nonquantized. Instead, the material behaves as though reacting to a high-frequency electric field. Manipulating MW penetration depth will be vital to develop the flow processes that underpin manufacturing and mass production.

本文言語英語
ページ(範囲)1170-1206
ページ数37
ジャーナルChemical Reviews
114
2
DOI
出版ステータス出版済み - 1 22 2014

All Science Journal Classification (ASJC) codes

  • 化学 (全般)

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