Molecular aggregation states of silsesquioxane-terminated polystyrene in polystyrene thin film

Kyota Miyamoto, Nao Hosaka, Motoyasu Kobayashi, Hideyuki Otsuka, Naoya Torikai, Atsushi Takahara

研究成果: 著書/レポートタイプへの貢献会議での発言

抄録

Organic-inorganic hybrid polymers (PS-POSS), which were polystyrene (PS) with polyhedral oligomeric silsesquioxane (POSS) end group, were prepared by nitroxide-mediated radical polymerization. Blend films composed of PS-POSS and PS were spin-coated from their toluene solution onto cleaned silicon wafer. The dispersibility of POSS in PS thin films was improved by the introduction of POSS as the chain end groups of PS. The addition of PS-POSS to PS thin film can stabilize the film against dewetting. Neutron reflectivity measurements revealed that PS-POSS formed enriched layer at the surface and interface of the film. The segregation of the PS-POSS, which changes the surface and interface free energy of the film, can be an important factor in the dewetting inhibition effect.

元の言語英語
ホスト出版物のタイトルPolymer Preprints, Japan - 55th SPSJ Annual Meeting
ページ1228
ページ数1
55
エディション1
出版物ステータス出版済み - 2006
イベント55th SPSJ Annual Meeting - Nagoya, 日本
継続期間: 5 24 20065 26 2006

その他

その他55th SPSJ Annual Meeting
日本
Nagoya
期間5/24/065/26/06

Fingerprint

Polystyrenes
Agglomeration
Thin films
Free radical polymerization
Silicon wafers
Free energy
Toluene
Neutrons
Polymers

All Science Journal Classification (ASJC) codes

  • Engineering(all)

これを引用

Miyamoto, K., Hosaka, N., Kobayashi, M., Otsuka, H., Torikai, N., & Takahara, A. (2006). Molecular aggregation states of silsesquioxane-terminated polystyrene in polystyrene thin film. : Polymer Preprints, Japan - 55th SPSJ Annual Meeting (1 版, 巻 55, pp. 1228)

Molecular aggregation states of silsesquioxane-terminated polystyrene in polystyrene thin film. / Miyamoto, Kyota; Hosaka, Nao; Kobayashi, Motoyasu; Otsuka, Hideyuki; Torikai, Naoya; Takahara, Atsushi.

Polymer Preprints, Japan - 55th SPSJ Annual Meeting. 巻 55 1. 編 2006. p. 1228.

研究成果: 著書/レポートタイプへの貢献会議での発言

Miyamoto, K, Hosaka, N, Kobayashi, M, Otsuka, H, Torikai, N & Takahara, A 2006, Molecular aggregation states of silsesquioxane-terminated polystyrene in polystyrene thin film. : Polymer Preprints, Japan - 55th SPSJ Annual Meeting. 1 Edn, 巻. 55, pp. 1228, 55th SPSJ Annual Meeting, Nagoya, 日本, 5/24/06.
Miyamoto K, Hosaka N, Kobayashi M, Otsuka H, Torikai N, Takahara A. Molecular aggregation states of silsesquioxane-terminated polystyrene in polystyrene thin film. : Polymer Preprints, Japan - 55th SPSJ Annual Meeting. 1 版 巻 55. 2006. p. 1228
Miyamoto, Kyota ; Hosaka, Nao ; Kobayashi, Motoyasu ; Otsuka, Hideyuki ; Torikai, Naoya ; Takahara, Atsushi. / Molecular aggregation states of silsesquioxane-terminated polystyrene in polystyrene thin film. Polymer Preprints, Japan - 55th SPSJ Annual Meeting. 巻 55 1. 版 2006. pp. 1228
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