Molecular design of synthetic receptors with dynamic, imprinting, and allosteric functions

Seiji Shinkai, Masayuki Takeuchi

研究成果: ジャーナルへの寄稿学術誌査読

34 被引用数 (Scopus)

抄録

Sugar recognition in an aqueous system has been achieved using a boronic acid-diol interaction. Combination with an intramolecular amino group has enabled us to read out the binding process as a change in the fluorescence intensity. This novel sugar-sensing method has been combined with a concept of "molecular machinery", providing a new guest-binding mode with allosteric functions. When this method is combined with a concept of "molecular imprinting", it becomes possible to design sugar-selective receptors created by a combinatorial method. The sugar recognition event is useful as a trigger to control molecular assemblies such as micelles, membranes, vesicles, and gels.

本文言語英語
ページ(範囲)40-51
ページ数12
ジャーナルBulletin of the Chemical Society of Japan
78
1
DOI
出版ステータス出版済み - 1月 2005

!!!All Science Journal Classification (ASJC) codes

  • 化学 (全般)

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