Molecular-salt hybrids; Integration of ammonia borane into lithium halides

Irene Cascallana-Matías; Joachim Breternitz; Annabelle Baker; Hallam Davis; Edmund J. Cussen; Duncan H. Gregory

doi:10.1039/c9qi00099b

Molecular-salt hybrids; Integration of ammonia borane into lithium halides

Irene Cascallana-Matías, Joachim Breternitz, Annabelle Baker, Hallam Davis, Edmund J. Cussen, Duncan H. Gregory

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

1 被引用数 (Scopus)

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New molecular-salt-like hybrids contain ammonia borane (AB) in co-existence with lithium halides in single lattices. [LiI](NH₃BH₃) and [LiI](NH₃BH₃)₂ are members of a generic [LiX]_m(AB)_n (X = I^-, BH₄^-; m, n = integer) materials family which release hydrogen on decomposition and demonstrate Li⁺-ion conductivity more than two orders of magnitude higher than either LiBH₄ or LiI.

本文言語	英語
ページ（範囲）	808-812
ページ数	5
ジャーナル	Inorganic Chemistry Frontiers
巻	6
号	3
DOI	https://doi.org/10.1039/c9qi00099b
出版ステータス	出版済み - 3月 2019
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

無機化学

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10.1039/c9qi00099b

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title = "Molecular-salt hybrids; Integration of ammonia borane into lithium halides",

abstract = "New molecular-salt-like hybrids contain ammonia borane (AB) in co-existence with lithium halides in single lattices. [LiI](NH3BH3) and [LiI](NH3BH3)2 are members of a generic [LiX]m(AB)n (X = I-, BH4-; m, n = integer) materials family which release hydrogen on decomposition and demonstrate Li+-ion conductivity more than two orders of magnitude higher than either LiBH4 or LiI.",

author = "Irene Cascallana-Mat{\'i}as and Joachim Breternitz and Annabelle Baker and Hallam Davis and Cussen, {Edmund J.} and Gregory, {Duncan H.}",

note = "Publisher Copyright: {\textcopyright} 2019 the Partner Organisations.",

year = "2019",

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doi = "10.1039/c9qi00099b",

language = "English",

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AU - Cascallana-Matías, Irene

AU - Breternitz, Joachim

AU - Baker, Annabelle

AU - Davis, Hallam

AU - Cussen, Edmund J.

AU - Gregory, Duncan H.

PY - 2019/3

Y1 - 2019/3

N2 - New molecular-salt-like hybrids contain ammonia borane (AB) in co-existence with lithium halides in single lattices. [LiI](NH3BH3) and [LiI](NH3BH3)2 are members of a generic [LiX]m(AB)n (X = I-, BH4-; m, n = integer) materials family which release hydrogen on decomposition and demonstrate Li+-ion conductivity more than two orders of magnitude higher than either LiBH4 or LiI.

AB - New molecular-salt-like hybrids contain ammonia borane (AB) in co-existence with lithium halides in single lattices. [LiI](NH3BH3) and [LiI](NH3BH3)2 are members of a generic [LiX]m(AB)n (X = I-, BH4-; m, n = integer) materials family which release hydrogen on decomposition and demonstrate Li+-ion conductivity more than two orders of magnitude higher than either LiBH4 or LiI.

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SN - 2052-1545

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Molecular-salt hybrids; Integration of ammonia borane into lithium halides

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