Multi-step spin crossover accompanied by symmetry breaking in an Fe III complex: Crystallographic evidence and DFT studies

研究成果: ジャーナルへの寄稿学術誌査読

72 被引用数 (Scopus)

抄録

Spin doctor: A mononuclear ferric complex [Fe(H-5-Br-thsa)(5-Br-thsa)] ×H2O (1) (H2-5-Br-thsa=5-bromo-2-hydroxybenzylidene) hydrazinecarbothioamide) was synthesized and its magnetic properties and structure were investigated by DFT calculations. This complex shows unprecedented reversible, six/five-step spin-crossover behavior accompanied by symmetry breaking. More importantly, each step in the multi-step transition was successfully characterized by single-crystal X-ray diffraction.

本文言語英語
ページ(範囲)12948-12952
ページ数5
ジャーナルChemistry - A European Journal
19
39
DOI
出版ステータス出版済み - 9月 23 2013

!!!All Science Journal Classification (ASJC) codes

  • 触媒
  • 有機化学

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