Multi-step spin crossover accompanied by symmetry breaking in an Fe III complex: Crystallographic evidence and DFT studies

研究成果: Contribution to journalArticle

52 引用 (Scopus)

抜粋

Spin doctor: A mononuclear ferric complex [Fe(H-5-Br-thsa)(5-Br-thsa)] ×H2O (1) (H2-5-Br-thsa=5-bromo-2-hydroxybenzylidene) hydrazinecarbothioamide) was synthesized and its magnetic properties and structure were investigated by DFT calculations. This complex shows unprecedented reversible, six/five-step spin-crossover behavior accompanied by symmetry breaking. More importantly, each step in the multi-step transition was successfully characterized by single-crystal X-ray diffraction.

元の言語英語
ページ(範囲)12948-12952
ページ数5
ジャーナルChemistry - A European Journal
19
発行部数39
DOI
出版物ステータス出版済み - 9 23 2013

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

フィンガープリント Multi-step spin crossover accompanied by symmetry breaking in an Fe <sup>III</sup> complex: Crystallographic evidence and DFT studies' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用