N-(carbamoylmethyl)pyridinium perchlorate and N-(carbamoylmethyl)-W-methyl-4,4′-bipyridinium diperchlorate hydrate

Ken Sakai, Yoshie Ikuta, Meiko Shiomi, Tsuyoshi Tamane, Yasushi Tomita, Taro Tsubomura, Nobukatsu Nemoto

研究成果: Contribution to journalArticle査読

12 被引用数 (Scopus)

抄録

The title compounds, C7H9N2O+.ClO- 4, (1), and C13H15N3O2+.ClO- 4.H2O, (2), have been synthesized and their crystal structures determined. The C-N(carbamoyl) bond in each compound has some double-bond character [bond lengths 1.319(5) for (1) and 1.325 (7) Å for (2)], indicating that the sp2 hybridization is delocalized over the O-C-N(carbamoyl) unit. The carbamoylmethyl plane is canted with respect to the attached pyridinium plane at an angle of 63.5 (2) for (1) and 79.1 (2)° for (2). Two major conformers have been found in the molecular mechanics calculations performed on the N-carbamoylmethylpyridinium cation.

本文言語英語
ページ(範囲)331-334
ページ数4
ジャーナルActa Crystallographica Section C: Crystal Structure Communications
53
3
DOI
出版ステータス出版済み - 3 15 1997
外部発表はい

All Science Journal Classification (ASJC) codes

  • Biochemistry, Genetics and Molecular Biology(all)

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