抄録
A skeleton of N-confused porphyrin (NC-porphine) has been synthesized for the first time, through a [3+1] coupling reaction. A completely planar inner 3H tautomeric form was found in the crystals, and the molecular packing shows a sandwich herringbone structure similar to that of normal porphine, whilst some of the spectroscopic properties demonstrate systematic substituent effects by the meso-phenyl groups on the N-confused porphyrin.
本文言語 | 英語 |
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ページ(範囲) | 3887-3890 |
ページ数 | 4 |
ジャーナル | European Journal of Organic Chemistry |
号 | 18 |
DOI | |
出版ステータス | 出版済み - 9月 12 2005 |
!!!All Science Journal Classification (ASJC) codes
- 物理化学および理論化学
- 有機化学