N-Confused Porphyrin-aza-Dipyrrin Chimera: A Versatile Metal Coordination Ligand Using its Unique NH Tautomerism

Masaya Fukuda, Shigeki Mori, Hiroyuki Furuta, Soji Shimizu

研究成果: ジャーナルへの寄稿記事

3 引用 (Scopus)

抄録

A novel N-confused porphyrin (NCP) analogue bearing an external aza-dipyrrin-like coordination site was synthesized by a Schiff-base forming reaction of N-confused oxoporphyrin and 2-aminopyridine derivatives. The chimera molecule enhances the intrinsic NH tautomerism of NCP to enable four possible tautomeric structures, three of which were identified by metal coordination.

元の言語英語
ページ(範囲)1697-1702
ページ数6
ジャーナルChemistry - An Asian Journal
14
発行部数10
DOI
出版物ステータス出版済み - 5 15 2019

Fingerprint

Porphyrins
Bearings (structural)
Metals
Ligands
Schiff Bases
Derivatives
Molecules
alpha-aminopyridine

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Biochemistry
  • Organic Chemistry

これを引用

N-Confused Porphyrin-aza-Dipyrrin Chimera : A Versatile Metal Coordination Ligand Using its Unique NH Tautomerism. / Fukuda, Masaya; Mori, Shigeki; Furuta, Hiroyuki; Shimizu, Soji.

:: Chemistry - An Asian Journal, 巻 14, 番号 10, 15.05.2019, p. 1697-1702.

研究成果: ジャーナルへの寄稿記事

@article{8151a72d8ff444f4b61a3c92f7aea110,
title = "N-Confused Porphyrin-aza-Dipyrrin Chimera: A Versatile Metal Coordination Ligand Using its Unique NH Tautomerism",
abstract = "A novel N-confused porphyrin (NCP) analogue bearing an external aza-dipyrrin-like coordination site was synthesized by a Schiff-base forming reaction of N-confused oxoporphyrin and 2-aminopyridine derivatives. The chimera molecule enhances the intrinsic NH tautomerism of NCP to enable four possible tautomeric structures, three of which were identified by metal coordination.",
author = "Masaya Fukuda and Shigeki Mori and Hiroyuki Furuta and Soji Shimizu",
year = "2019",
month = "5",
day = "15",
doi = "10.1002/asia.201801750",
language = "English",
volume = "14",
pages = "1697--1702",
journal = "Chemistry - An Asian Journal",
issn = "1861-4728",
publisher = "John Wiley and Sons Ltd",
number = "10",

}

TY - JOUR

T1 - N-Confused Porphyrin-aza-Dipyrrin Chimera

T2 - A Versatile Metal Coordination Ligand Using its Unique NH Tautomerism

AU - Fukuda, Masaya

AU - Mori, Shigeki

AU - Furuta, Hiroyuki

AU - Shimizu, Soji

PY - 2019/5/15

Y1 - 2019/5/15

N2 - A novel N-confused porphyrin (NCP) analogue bearing an external aza-dipyrrin-like coordination site was synthesized by a Schiff-base forming reaction of N-confused oxoporphyrin and 2-aminopyridine derivatives. The chimera molecule enhances the intrinsic NH tautomerism of NCP to enable four possible tautomeric structures, three of which were identified by metal coordination.

AB - A novel N-confused porphyrin (NCP) analogue bearing an external aza-dipyrrin-like coordination site was synthesized by a Schiff-base forming reaction of N-confused oxoporphyrin and 2-aminopyridine derivatives. The chimera molecule enhances the intrinsic NH tautomerism of NCP to enable four possible tautomeric structures, three of which were identified by metal coordination.

UR - http://www.scopus.com/inward/record.url?scp=85060934667&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85060934667&partnerID=8YFLogxK

U2 - 10.1002/asia.201801750

DO - 10.1002/asia.201801750

M3 - Article

C2 - 30706687

AN - SCOPUS:85060934667

VL - 14

SP - 1697

EP - 1702

JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

SN - 1861-4728

IS - 10

ER -