N-Confused Porphyrin Metal Complexes with an Axial Pyridine Directly Tethered from an Inner Carbon: A Bioinspired Ligand as a Versatile Platform for Catalysis

Takaaki Miyazaki, Takaaki Yamamoto, Shunichi Mashita, Yuya Deguchi, Kazuki Fukuyama, Masatoshi Ishida, Shigeki Mori, Hiroyuki Furuta

研究成果: Contribution to journalArticle査読

15 被引用数 (Scopus)

抄録

Bioinspired pentadentate ligand N-confused porphyrin (NCP) bearing a 2-mercaptopyridine group and its RuII and CoIII complexes were synthesized. Their structures were revealed by single-crystal X-ray crystallographic analysis. Installation of an axial thiopyridine ligand shifts the redox potentials negatively and enhances the catalytic activity largely, which was demonstrated in the cyclopropanation reaction using the Co complex.

本文言語英語
ページ(範囲)203-207
ページ数5
ジャーナルEuropean Journal of Inorganic Chemistry
2018
2
DOI
出版ステータス出版済み - 1 23 2018

All Science Journal Classification (ASJC) codes

  • 無機化学

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