(N-Methyl-4,4′-bipyridinium)(2,2′: 6′,2″- terpyridine)platinum(II) triperchlorate monohydrate

Ken Sakai, Mai Kurashima, Manabu Osada, Satoru Takahashi

研究成果: ジャーナルへの寄稿記事

8 引用 (Scopus)

抄録

In the title compound, [Pt(C15H11N 3)(C11H11N2)](ClO4) 3-H2O, the PtN4 coordination plane is distorted from a planar geometry owing to the relatively strong intermolecular terpy-terpy interactions, giving rise to a bent structure with respect to the terpy moiety (terpy = 2,2′:6′,2″-terpyridine). The coordinated pyridyl plane of N-methyl-4,4′-bipyridinium (MQ) is inclined by 81.7 (1)° with respect to the Pt coordination plane. The dihedral angle between the two pyridyl planes within MQ is 33.5 (2)°.

元の言語英語
ジャーナルActa Crystallographica Section E: Structure Reports Online
59
発行部数7
DOI
出版物ステータス出版済み - 7 1 2003
外部発表Yes

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Dihedral angle
Platinum
platinum
Geometry
dihedral angle
geometry
interactions
perchlorate

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Structural Biology

これを引用

(N-Methyl-4,4′-bipyridinium)(2,2′ : 6′,2″- terpyridine)platinum(II) triperchlorate monohydrate. / Sakai, Ken; Kurashima, Mai; Osada, Manabu; Takahashi, Satoru.

:: Acta Crystallographica Section E: Structure Reports Online, 巻 59, 番号 7, 01.07.2003.

研究成果: ジャーナルへの寄稿記事

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abstract = "In the title compound, [Pt(C15H11N 3)(C11H11N2)](ClO4) 3-H2O, the PtN4 coordination plane is distorted from a planar geometry owing to the relatively strong intermolecular terpy-terpy interactions, giving rise to a bent structure with respect to the terpy moiety (terpy = 2,2′:6′,2″-terpyridine). The coordinated pyridyl plane of N-methyl-4,4′-bipyridinium (MQ) is inclined by 81.7 (1)° with respect to the Pt coordination plane. The dihedral angle between the two pyridyl planes within MQ is 33.5 (2)°.",
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T1 - (N-Methyl-4,4′-bipyridinium)(2,2′

T2 - 6′,2″- terpyridine)platinum(II) triperchlorate monohydrate

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AU - Kurashima, Mai

AU - Osada, Manabu

AU - Takahashi, Satoru

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N2 - In the title compound, [Pt(C15H11N 3)(C11H11N2)](ClO4) 3-H2O, the PtN4 coordination plane is distorted from a planar geometry owing to the relatively strong intermolecular terpy-terpy interactions, giving rise to a bent structure with respect to the terpy moiety (terpy = 2,2′:6′,2″-terpyridine). The coordinated pyridyl plane of N-methyl-4,4′-bipyridinium (MQ) is inclined by 81.7 (1)° with respect to the Pt coordination plane. The dihedral angle between the two pyridyl planes within MQ is 33.5 (2)°.

AB - In the title compound, [Pt(C15H11N 3)(C11H11N2)](ClO4) 3-H2O, the PtN4 coordination plane is distorted from a planar geometry owing to the relatively strong intermolecular terpy-terpy interactions, giving rise to a bent structure with respect to the terpy moiety (terpy = 2,2′:6′,2″-terpyridine). The coordinated pyridyl plane of N-methyl-4,4′-bipyridinium (MQ) is inclined by 81.7 (1)° with respect to the Pt coordination plane. The dihedral angle between the two pyridyl planes within MQ is 33.5 (2)°.

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