Nano-rod structure of poly(ethylenedioxythiophene) and poly(pyrrole) as created by electrochemical polymerization using anionic porphyrin aggregates as template

Tsukasa Hatano, Masayuki Takeuchi, Atsushi Ikeda, Seiji Shinkai

研究成果: ジャーナルへの寄稿学術誌査読

51 被引用数 (Scopus)

抄録

(Matrix presented) It was found that a one-dimensional rodlike structure of 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin (TPPS) in water acts as a powerful template for electrochemical polymerization of ethylenedioxathiophene (EDOT) and pyrrole on an ITO electrode. Examination using CV and UV-vis spectroscopic examinations established that J-aggregated TPPS molecules are entrapped in the resultant poly(EDOT) and poly(pyrrole) films. SEM observation established that these monomers are electrochemically oxidized to grow up to a nanosized rodlike structure, reflecting the aggregation structure of TPPS.

本文言語英語
ページ(範囲)1395-1398
ページ数4
ジャーナルOrganic Letters
5
9
DOI
出版ステータス出版済み - 5月 1 2003

!!!All Science Journal Classification (ASJC) codes

  • 生化学
  • 物理化学および理論化学
  • 有機化学

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