Nature of ore fluid at the sopokomil Zn-Pb deposit, North Sumatra, Indonesia: Implications for metal transport and sulfide deposition

Tomy Alvin Rivai, Syafrizal, Kotaro Yonezu, Kenzo Sanematsu, Koichiro Watanabe

研究成果: Contribution to journalArticle査読

抄録

Little is known about the nature of ore fluid at the Sopokomil shale-hosted massive sulfide Zn-Pb deposit (North Sumatra, Indonesia). We therefore investigated its ore-fluid salinities, temperatures, densities, redox state, and pH using fluid inclusion microthermometry, sphalerite composition, and thermodynamic modelling. The fluid salinities and temperatures were ≈6 wt.% NaCl equiv and ≈165 °C, respectively, corresponding to an ore fluid less dense than seawater (≈0.96 g/mL). Sphalerite contains ≈9.9 mole% FeS in the stratiform ore and ≈3.4 mole% FeS in the feeder ore, suggesting a reduced fluid, which must have been acidic to be fertile. Such redox state and acidity invoke fluid dilution as the sulfide depositional mechanism. The bulk of the sulfides were precipitated in the early stage of mixing, within T = 165–155 °C. Key ingredients of sphalerite and galena at Sopokomil include (1) Zn that was primarily transported as ZnCl+, (2) Pb that predominantly occurred as PbCl2(aq), and (3) S that was largely supplied by marine sediment porewater. This study highlights the significance of a dramatic shift in thermal and chemical equilibrium induced by fluid dilution in the making of the first significant shale-hosted massive sulfide Zn-Pb deposit in Indonesia.

本文言語英語
論文番号298
ジャーナルGeosciences (Switzerland)
11
7
DOI
出版ステータス出版済み - 7 2021

All Science Journal Classification (ASJC) codes

  • 地球惑星科学(全般)

フィンガープリント

「Nature of ore fluid at the sopokomil Zn-Pb deposit, North Sumatra, Indonesia: Implications for metal transport and sulfide deposition」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル