New 3-D bimetallic magnetic compounds, [Ni(dipn)]3[M(CN) 6]2·7H2O (MIII = Fe, Co; dipn = N,N-di(3-aminopropyl)amine)

Masaaki Ohba, Mitsuteru Yamada, Naoki Usukp, Hisashi Ökawa

研究成果: Contribution to journalArticle

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New cyanide-bridged bimetallic compounds of the formula [Ni(dipn)] 3[M(CN)6]2·7H2O (M III = Fe (1), Co (2); dipn = N,N-di(3-aminopropyl)amine) were prepared and their crystal structures and magnetic properties were investigated. They are isostructural. In the crystal of 1 each [Fe(CN) makes bond to three [Ni(dipn)]2- cations to form a 2-D sheet and the 2-D sheets are connected by [Ni(dipn)(H2O)]2- cations providing a 3-D network structure. 1 shows a ferromagnetic ordering in ihe bulk with T C = 7.8 K.

ジャーナルMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
出版物ステータス出版済み - 2002

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics

フィンガープリント New 3-D bimetallic magnetic compounds, [Ni(dipn)]<sub>3</sub>[M(CN) <sub>6</sub>]<sub>2</sub>·7H<sub>2</sub>O (M<sup>III</sup> = Fe, Co; dipn = N,N-di(3-aminopropyl)amine)' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

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